A Deoximation Method for Deprotection of Ketones and Aldhydes Using a Graphene-Oxide-Based Co-catalysts System
Tong, Qiaolin1; Liu, Yang1; Gao, Xuezhi1; Fan, Zhanfang1; Liu, Tianfu2; Li, Bo2; Su, Dangsheng2,3; Wang, Qinghe1; Cheng, Maosheng1
刊名ADVANCED SYNTHESIS & CATALYSIS
2019-07-02
卷号361期号:13页码:3137-3145
关键词Deoximation Graphene oxide Sodium nitrite Air Oximes
ISSN号1615-4150
DOI10.1002/adsc.201900202
通讯作者Liu, Yang(y.liu@syphu.edu.cn) ; Wang, Qinghe(qinghe-wang@163.com) ; Cheng, Maosheng(mscheng@syphu.edu.cn)
英文摘要The deoximation of a wide range of ketoximes and aldoximes to their corresponding carbonyl compounds with high yields has been achieved using graphene oxide (GO) and sodium nitrite (NaNO2) as highly efficient catalysts and air as the green oxidant under mild conditions. The mechanism of deprotection and recycling use of catalyst were revealed in deep experiment. The carboxylic acid groups on the GO were essential for high catalytic activity.
资助项目National Natural Science Foundation of China[81473087] ; National Natural Science Foundation of China[81872752] ; Program for Liaoning Innovative Talents in University[LR2017043] ; Career Development Support Plan for Young and Middle-aged Teachers in Shenyang Pharmaceutical University[ZQN2016005]
WOS关键词METAL-FREE CATALYST ; AEROBIC OXIDATION ; OXIMES ; EFFICIENT ; CARBOCATALYST ; PHOTOCATALYST ; ETHYLBENZENE ; CYCLOHEXENE
WOS研究方向Chemistry
语种英语
出版者WILEY-V C H VERLAG GMBH
WOS记录号WOS:000484142600013
资助机构National Natural Science Foundation of China ; National Natural Science Foundation of China ; Program for Liaoning Innovative Talents in University ; Program for Liaoning Innovative Talents in University ; Career Development Support Plan for Young and Middle-aged Teachers in Shenyang Pharmaceutical University ; Career Development Support Plan for Young and Middle-aged Teachers in Shenyang Pharmaceutical University ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Program for Liaoning Innovative Talents in University ; Program for Liaoning Innovative Talents in University ; Career Development Support Plan for Young and Middle-aged Teachers in Shenyang Pharmaceutical University ; Career Development Support Plan for Young and Middle-aged Teachers in Shenyang Pharmaceutical University ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Program for Liaoning Innovative Talents in University ; Program for Liaoning Innovative Talents in University ; Career Development Support Plan for Young and Middle-aged Teachers in Shenyang Pharmaceutical University ; Career Development Support Plan for Young and Middle-aged Teachers in Shenyang Pharmaceutical University ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Program for Liaoning Innovative Talents in University ; Program for Liaoning Innovative Talents in University ; Career Development Support Plan for Young and Middle-aged Teachers in Shenyang Pharmaceutical University ; Career Development Support Plan for Young and Middle-aged Teachers in Shenyang Pharmaceutical University
内容类型期刊论文
源URL[http://cas-ir.dicp.ac.cn/handle/321008/173119]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者Liu, Yang; Wang, Qinghe; Cheng, Maosheng
作者单位1.Shenyang Pharmaceut Univ, Sch Pharmaceut Engn, Minist Educ, Key Lab Struct Based Drug Design & Discovery, Shenyang 110016, Liaoning, Peoples R China
2.Chinese Acad Sci, Inst Met Res, Shenyang 110016, Liaoning, Peoples R China
3.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
推荐引用方式
GB/T 7714
Tong, Qiaolin,Liu, Yang,Gao, Xuezhi,et al. A Deoximation Method for Deprotection of Ketones and Aldhydes Using a Graphene-Oxide-Based Co-catalysts System[J]. ADVANCED SYNTHESIS & CATALYSIS,2019,361(13):3137-3145.
APA Tong, Qiaolin.,Liu, Yang.,Gao, Xuezhi.,Fan, Zhanfang.,Liu, Tianfu.,...&Cheng, Maosheng.(2019).A Deoximation Method for Deprotection of Ketones and Aldhydes Using a Graphene-Oxide-Based Co-catalysts System.ADVANCED SYNTHESIS & CATALYSIS,361(13),3137-3145.
MLA Tong, Qiaolin,et al."A Deoximation Method for Deprotection of Ketones and Aldhydes Using a Graphene-Oxide-Based Co-catalysts System".ADVANCED SYNTHESIS & CATALYSIS 361.13(2019):3137-3145.
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