Intermolecular Chemistry in Solid Polymer Electrolytes for High-Energy-Density Lithium Batteries

doi:10.1002/adma.201902029

	Intermolecular Chemistry in Solid Polymer Electrolytes for High-Energy-Density Lithium Batteries
	Zhou, Qian 1,2; Ma, Jun 1,2; Dong, Shanmu 1,2; Li, Xianfeng 1,3; Cui, Guanglei 1,2
刊名	ADVANCED MATERIALS
	2019-08-22
页码	21
关键词	high-voltage compatibility intermolecular interaction ionic conductivity polymer electrolytes solid lithium batteries
ISSN号	0935-9648
DOI	10.1002/adma.201902029
通讯作者	Dong, Shanmu(dongsm@qibebt.ac.cn) ; Cui, Guanglei(cuigl@qibebt.ac.cn)
英文摘要	Solid polymer electrolytes (SPEs) have aroused wide interest in lithium batteries because of their sufficient mechanical properties, superior safety performances, and excellent processability. However, ionic conductivity and high-voltage compatibility of SPEs are still yet to meet the requirement of future energy-storage systems, representing significant barriers to progress. In this regard, intermolecular interactions in SPEs have attracted attention, and they can significantly impact on the Li+ motion and frontier orbital energy level of SPEs. Recent advances in improving electrochemcial performance of SPEs are reviewed, and the underlying mechanism of these proposed strategies related to intermolecular interaction is discussed, including ion-dipole, hydrogen bonds, pi-pi stacking, and Lewis acid-base interactions. It is hoped that this review can inspire a deeper consideration on this critical issue, which can pave new pathway to improve ionic conductivity and high-voltage performance of SPEs.
资助项目	Strategic Priority Research Program of the Chinese Academy of Sciences[XDA22000000] ; Youth Innovation Promotion Association of CAS[2016193] ; National Key R&D Program of China[2018YFB0104300] ; National Natural Science Foundation for Distinguished Young Scholars of China[51625204] ; Key research and development plan of Shandong Province[2018GGX104016] ; Key Scientific and Technological Innovation Project of Shandong[2017CXZC0505] ; Qingdao Post-doctoral Applied Research Project ; Think-Tank Mutual Fund of Qingdao Energy Storage Industry Scientific Research ; 135 Projects Fund of CAS-QIBEBT Director Innovation Foundation ; Qingdao Science and Technology Program[17-1-1-26-jch] ; NSFC-Shandong Joint Fund[U1706229] ; Shandong Natural Science Foundation[ZR2018ZB0316]
WOS关键词	HIGH IONIC-CONDUCTIVITY ; ENHANCED ELECTROCHEMICAL PERFORMANCE ; POLY(ETHYLENE OXIDE) ; SUPERCONCENTRATED ELECTROLYTES ; COMPOSITE ELECTROLYTES ; MECHANICAL STRENGTH ; PLASTIC ELECTROLYTE ; TRANSPORT ; STABILITY ; SUCCINONITRILE
WOS研究方向	Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics
语种	英语
出版者	WILEY-V C H VERLAG GMBH
WOS记录号	WOS:000483161700001
资助机构	Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Youth Innovation Promotion Association of CAS ; Youth Innovation Promotion Association of CAS ; National Key R&D Program of China ; National Key R&D Program of China ; National Natural Science Foundation for Distinguished Young Scholars of China ; National Natural Science Foundation for Distinguished Young Scholars of China ; Key research and development plan of Shandong Province ; Key research and development plan of Shandong Province ; Key Scientific and Technological Innovation Project of Shandong ; Key Scientific and Technological Innovation Project of Shandong ; Qingdao Post-doctoral Applied Research Project ; Qingdao Post-doctoral Applied Research Project ; Think-Tank Mutual Fund of Qingdao Energy Storage Industry Scientific Research ; Think-Tank Mutual Fund of Qingdao Energy Storage Industry Scientific Research ; 135 Projects Fund of CAS-QIBEBT Director Innovation Foundation ; 135 Projects Fund of CAS-QIBEBT Director Innovation Foundation ; Qingdao Science and Technology Program ; Qingdao Science and Technology Program ; NSFC-Shandong Joint Fund ; NSFC-Shandong Joint Fund ; Shandong Natural Science Foundation ; Shandong Natural Science Foundation ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Youth Innovation Promotion Association of CAS ; Youth Innovation Promotion Association of CAS ; National Key R&D Program of China ; National Key R&D Program of China ; National Natural Science Foundation for Distinguished Young Scholars of China ; National Natural Science Foundation for Distinguished Young Scholars of China ; Key research and development plan of Shandong Province ; Key research and development plan of Shandong Province ; Key Scientific and Technological Innovation Project of Shandong ; Key Scientific and Technological Innovation Project of Shandong ; Qingdao Post-doctoral Applied Research Project ; Qingdao Post-doctoral Applied Research Project ; Think-Tank Mutual Fund of Qingdao Energy Storage Industry Scientific Research ; Think-Tank Mutual Fund of Qingdao Energy Storage Industry Scientific Research ; 135 Projects Fund of CAS-QIBEBT Director Innovation Foundation ; 135 Projects Fund of CAS-QIBEBT Director Innovation Foundation ; Qingdao Science and Technology Program ; Qingdao Science and Technology Program ; NSFC-Shandong Joint Fund ; NSFC-Shandong Joint Fund ; Shandong Natural Science Foundation ; Shandong Natural Science Foundation ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Youth Innovation Promotion Association of CAS ; Youth Innovation Promotion Association of CAS ; National Key R&D Program of China ; National Key R&D Program of China ; National Natural Science Foundation for Distinguished Young Scholars of China ; National Natural Science Foundation for Distinguished Young Scholars of China ; Key research and development plan of Shandong Province ; Key research and development plan of Shandong Province ; Key Scientific and Technological Innovation Project of Shandong ; Key Scientific and Technological Innovation Project of Shandong ; Qingdao Post-doctoral Applied Research Project ; Qingdao Post-doctoral Applied Research Project ; Think-Tank Mutual Fund of Qingdao Energy Storage Industry Scientific Research ; Think-Tank Mutual Fund of Qingdao Energy Storage Industry Scientific Research ; 135 Projects Fund of CAS-QIBEBT Director Innovation Foundation ; 135 Projects Fund of CAS-QIBEBT Director Innovation Foundation ; Qingdao Science and Technology Program ; Qingdao Science and Technology Program ; NSFC-Shandong Joint Fund ; NSFC-Shandong Joint Fund ; Shandong Natural Science Foundation ; Shandong Natural Science Foundation ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Youth Innovation Promotion Association of CAS ; Youth Innovation Promotion Association of CAS ; National Key R&D Program of China ; National Key R&D Program of China ; National Natural Science Foundation for Distinguished Young Scholars of China ; National Natural Science Foundation for Distinguished Young Scholars of China ; Key research and development plan of Shandong Province ; Key research and development plan of Shandong Province ; Key Scientific and Technological Innovation Project of Shandong ; Key Scientific and Technological Innovation Project of Shandong ; Qingdao Post-doctoral Applied Research Project ; Qingdao Post-doctoral Applied Research Project ; Think-Tank Mutual Fund of Qingdao Energy Storage Industry Scientific Research ; Think-Tank Mutual Fund of Qingdao Energy Storage Industry Scientific Research ; 135 Projects Fund of CAS-QIBEBT Director Innovation Foundation ; 135 Projects Fund of CAS-QIBEBT Director Innovation Foundation ; Qingdao Science and Technology Program ; Qingdao Science and Technology Program ; NSFC-Shandong Joint Fund ; NSFC-Shandong Joint Fund ; Shandong Natural Science Foundation ; Shandong Natural Science Foundation
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/172938]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Dong, Shanmu; Cui, Guanglei
作者单位	1.Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao Ind Energy Storage Res Inst, 189 Songling Rd, Qingdao 266101, Shandong, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, Div Energy Storage, Dalian Natl Lab Clean Energy, 457 Zhongshan Rd, Dalian 116023, Peoples R China
推荐引用方式 GB/T 7714	Zhou, Qian,Ma, Jun,Dong, Shanmu,et al. Intermolecular Chemistry in Solid Polymer Electrolytes for High-Energy-Density Lithium Batteries[J]. ADVANCED MATERIALS,2019:21.
APA	Zhou, Qian,Ma, Jun,Dong, Shanmu,Li, Xianfeng,&Cui, Guanglei.(2019).Intermolecular Chemistry in Solid Polymer Electrolytes for High-Energy-Density Lithium Batteries.ADVANCED MATERIALS,21.
MLA	Zhou, Qian,et al."Intermolecular Chemistry in Solid Polymer Electrolytes for High-Energy-Density Lithium Batteries".ADVANCED MATERIALS (2019):21.