Unraveling the coordination structure-performance relationship in Pt-1/Fe2O3 single-atom catalyst

doi:10.1038/s41467-019-12459-0

	Unraveling the coordination structure-performance relationship in Pt-1/Fe2O3 single-atom catalyst
	Ren, Yujing 2,3; Tang, Yan 1,4; Zhang, Leilei 2; Liu, Xiaoyan 2; Li, Lin 2; Miao, Shu 2; Su, Dang Sheng 2; Wang, Aiqin 2; Li, Jun 1,4,5; Zhang, Tao 2
刊名	NATURE COMMUNICATIONS
	2019-10-03
卷号	10 页码:9
ISSN号	2041-1723
DOI	10.1038/s41467-019-12459-0
通讯作者	Wang, Aiqin(aqwang@dicp.ac.cn) ; Li, Jun(junli@tsinghua.edu.cn) ; Zhang, Tao(taozhang@dicp.ac.cn)
英文摘要	Heterogeneous single-atom catalyst (SAC) opens a unique entry to establishing structure-performance relationship at the molecular level similar to that in homogeneous catalysis. The challenge lies in manipulating the coordination chemistry of single atoms without changing single-atom dispersion. Here, we develop an efficient synthetic method for SACs by using ethanediamine to chelate Pt cations and then removing the ethanediamine by a rapid thermal treatment (RTT) in inert atmosphere. The coordination chemistry of Pt single atoms on a Fe2O3 support is finely tuned by merely adjusting the RTT temperature. With the decrease in Pt-O coordination number, the oxidation state of Pt decreases, and consequently the hydrogenation activity increases to a record level without loss of chemoselectivity. The tunability of the local coordination chemistry, oxidation states of the metal, and the catalytic performance of single atoms reveals the unique role of SACs as a bridge between heterogeneous and homogeneous catalysis.
资助项目	National Science Foundation of China (NSFC)[21690080] ; National Science Foundation of China (NSFC)[21690084] ; National Science Foundation of China (NSFC)[21673228] ; National Science Foundation of China (NSFC)[21721004] ; National Science Foundation of China (NSFC)[21606227] ; NSFC[21590792] ; NSFC[91645203] ; Strategic Priority Research Program of the Chinese Academy of Sciences[XDB17020100] ; National Key Projects for Fundamental Research and Development of China[2016YFA0202801]
WOS关键词	N-C CATALYST ; CHEMOSELECTIVE HYDROGENATION ; HETEROGENEOUS CATALYSIS ; ACTIVE GOLD ; OXIDATION ; IDENTIFICATION ; LIGANDS ; DESIGN ; SITES ; IONS
WOS研究方向	Science & Technology - Other Topics
语种	英语
出版者	NATURE PUBLISHING GROUP
WOS记录号	WOS:000488774200016
资助机构	National Science Foundation of China (NSFC) ; National Science Foundation of China (NSFC) ; NSFC ; NSFC ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; National Key Projects for Fundamental Research and Development of China ; National Key Projects for Fundamental Research and Development of China ; National Science Foundation of China (NSFC) ; National Science Foundation of China (NSFC) ; NSFC ; NSFC ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; National Key Projects for Fundamental Research and Development of China ; National Key Projects for Fundamental Research and Development of China ; National Science Foundation of China (NSFC) ; National Science Foundation of China (NSFC) ; NSFC ; NSFC ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; National Key Projects for Fundamental Research and Development of China ; National Key Projects for Fundamental Research and Development of China ; National Science Foundation of China (NSFC) ; National Science Foundation of China (NSFC) ; NSFC ; NSFC ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; National Key Projects for Fundamental Research and Development of China ; National Key Projects for Fundamental Research and Development of China
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/172534]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Wang, Aiqin; Li, Jun; Zhang, Tao
作者单位	1.Tsinghua Univ, Minist Educ, Key Lab Organ Optoelect & Mol Engn, Beijing 100084, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 4.Tsinghua Univ, Dept Chem, Beijing 100084, Peoples R China 5.Southern Univ Sci & Technol, Dept Chem, Shenzhen 518055, Peoples R China
推荐引用方式 GB/T 7714	Ren, Yujing,Tang, Yan,Zhang, Leilei,et al. Unraveling the coordination structure-performance relationship in Pt-1/Fe2O3 single-atom catalyst[J]. NATURE COMMUNICATIONS,2019,10:9.
APA	Ren, Yujing.,Tang, Yan.,Zhang, Leilei.,Liu, Xiaoyan.,Li, Lin.,...&Zhang, Tao.(2019).Unraveling the coordination structure-performance relationship in Pt-1/Fe2O3 single-atom catalyst.NATURE COMMUNICATIONS,10,9.
MLA	Ren, Yujing,et al."Unraveling the coordination structure-performance relationship in Pt-1/Fe2O3 single-atom catalyst".NATURE COMMUNICATIONS 10(2019):9.