Aliphatic amines modified CoO nanoparticles for catalytic oxidation of aromatic hydrocarbon with molecular oxygen

doi:10.1016/S1872-2067(19)63413-3

	Aliphatic amines modified CoO nanoparticles for catalytic oxidation of aromatic hydrocarbon with molecular oxygen
	Liu, Meng 1,2; Shi, Song 2; Zhao, Li 1,2; Chen, Chen 2,3; Gao, Jin 2; Xu, Jie 2
刊名	CHINESE JOURNAL OF CATALYSIS
	2019-10-01
卷号	40 期号:10 页码:1488-1493
关键词	Hydrocarbon oxidation Hydrophobic modification Amines coating Cobalt oxide Surface modification
ISSN号	0253-9837
DOI	10.1016/S1872-2067(19)63413-3
通讯作者	Shi, Song(shisong@dicp.ac.cn) ; Xu, Jie(xujie@dicp.ac.cn)
英文摘要	The surface modification of metal oxides using organic modifiers is a potential strategy for enhancing their catalytic performances. In this study, a hydrophobic surface amine-modified CoO catalyst with a water contact angle of 143 was fabricated. The catalyst was characterized by XRD, TGA, FT-IR, HR-TEM, and XPS. The results showed that the fabricated catalyst performed better than the hydrophilic commercial CoO nanoparticle in the process of aromatic hydrocarbon oxidation. After the amines modification, commercial CoO also became hydrophobic and improved conversion of ethylbenzene was achieved. The surface modification of CoO with amines induced the hydrophobicity property, which could serve as a reference for the design of other hydrophobic catalysts. (C) 2019, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.
资助项目	National Natural Science Foundation of China[21790331] ; National Natural Science Foundation of China[21603218] ; Strategic Priority Research Program of Chinese Academy of Sciences[XDA21030400] ; Strategic Priority Research Program of Chinese Academy of Sciences[XDB17020300]
WOS关键词	SELECTIVE OXIDATION ; REDUCING AGENT ; ETHYLBENZENE ; NANOCRYSTALS ; CYCLOHEXANE ; PERFORMANCE ; OLEYLAMINE ; COBALT ; OXIDES ; CO3O4
WOS研究方向	Chemistry ; Engineering
语种	英语
出版者	SCIENCE PRESS
WOS记录号	WOS:000490625200005
资助机构	National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of Chinese Academy of Sciences ; Strategic Priority Research Program of Chinese Academy of Sciences ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of Chinese Academy of Sciences ; Strategic Priority Research Program of Chinese Academy of Sciences ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of Chinese Academy of Sciences ; Strategic Priority Research Program of Chinese Academy of Sciences ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of Chinese Academy of Sciences ; Strategic Priority Research Program of Chinese Academy of Sciences
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/172493]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Shi, Song; Xu, Jie
作者单位	1.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian Natl Lab Clean Energy, Dalian 116023, Liaoning, Peoples R China 3.Ningbo Univ, Sch Mat Sci & Chem Engn, Ningbo 315211, Zhejiang, Peoples R China
推荐引用方式 GB/T 7714	Liu, Meng,Shi, Song,Zhao, Li,et al. Aliphatic amines modified CoO nanoparticles for catalytic oxidation of aromatic hydrocarbon with molecular oxygen[J]. CHINESE JOURNAL OF CATALYSIS,2019,40(10):1488-1493.
APA	Liu, Meng,Shi, Song,Zhao, Li,Chen, Chen,Gao, Jin,&Xu, Jie.(2019).Aliphatic amines modified CoO nanoparticles for catalytic oxidation of aromatic hydrocarbon with molecular oxygen.CHINESE JOURNAL OF CATALYSIS,40(10),1488-1493.
MLA	Liu, Meng,et al."Aliphatic amines modified CoO nanoparticles for catalytic oxidation of aromatic hydrocarbon with molecular oxygen".CHINESE JOURNAL OF CATALYSIS 40.10(2019):1488-1493.