An experimental study on synthesis of glycolic acid via carbonylation of formaldehyde using PTFE membrane contactor

doi:10.1016/j.memsci.2019.05.073

	An experimental study on synthesis of glycolic acid via carbonylation of formaldehyde using PTFE membrane contactor
	Zhu, Zhihao 1,2; Kang, Guodong 2; Sun, Ying 2; Yu, Sha 1,2; Li, Meng 2; Xu, Jie 2; Cao, Yiming 2
刊名	JOURNAL OF MEMBRANE SCIENCE
	2019-09-15
卷号	586 页码:259-266
关键词	Carbonylation of formaldehyde Glycolic acid PTFE Membrane contactor Mass transfer
ISSN号	0376-7388
DOI	10.1016/j.memsci.2019.05.073
通讯作者	Kang, Guodong(kangguod@dicp.ac.cn) ; Cao, Yiming(ymcao@dicp.ac.cn)
英文摘要	The batch and continuous synthesis of glycolic acid via carbonylation of formaldehyde using high-temperature and high-pressure poly(tetrafluoroethylene) (PTFE) membrane contactor was demonstrated in this paper. The experiments in conventional stirred tank reactor were also conducted for comparison. The results showed that the yield of glycolic acid was significantly improved in membrane contactor system compared to the stirred tank reactor. At reaction temperature of 120 degrees C and reaction pressure of 5.0 MPa, the yield of glycolic acid was higher than 90% when the reaction time was 1 h, while it was only about 45% in the conventional stirred tank reactor. The enhancement of yield was due to the improvement of mass transfer or dispersion of CO in membrane contactor system, which could provide larger gas-liquid contact area and shorter mass transfer distance. The stability of PTFE hollow fibre membranes was also investigated by Fourier transform infrared (FTIR) spectroscopy, scanning electron microscopy (SEM), liquid entry pressure (LEP), bubble point (BP) and contact angle (CA) measurements. The characterizations indicated that PTFE membranes exhibited good chemical and thermal stability in this reaction system. This study provided new idea and reference for the carbonylation of formaldehyde and similar gas-liquid reactions.
资助项目	DICP[DMTO201604] ; Youth Innovation Promotion Association of the Chinese Academy of Sciences[2016171] ; LiaoNing Revitalization Talents Program[XLYC1807240]
WOS关键词	VAPOR-PHASE CARBONYLATION ; HOLLOW-FIBER MEMBRANES ; ETHYLENE-GLYCOL ; METHYL FORMATE ; DIMETHOXYMETHANE ; HETEROPOLYACIDS ; PRECURSORS ; CATALYSTS
WOS研究方向	Engineering ; Polymer Science
语种	英语
出版者	ELSEVIER SCIENCE BV
WOS记录号	WOS:000471097100027
资助机构	DICP ; DICP ; Youth Innovation Promotion Association of the Chinese Academy of Sciences ; Youth Innovation Promotion Association of the Chinese Academy of Sciences ; LiaoNing Revitalization Talents Program ; LiaoNing Revitalization Talents Program ; DICP ; DICP ; Youth Innovation Promotion Association of the Chinese Academy of Sciences ; Youth Innovation Promotion Association of the Chinese Academy of Sciences ; LiaoNing Revitalization Talents Program ; LiaoNing Revitalization Talents Program ; DICP ; DICP ; Youth Innovation Promotion Association of the Chinese Academy of Sciences ; Youth Innovation Promotion Association of the Chinese Academy of Sciences ; LiaoNing Revitalization Talents Program ; LiaoNing Revitalization Talents Program ; DICP ; DICP ; Youth Innovation Promotion Association of the Chinese Academy of Sciences ; Youth Innovation Promotion Association of the Chinese Academy of Sciences ; LiaoNing Revitalization Talents Program ; LiaoNing Revitalization Talents Program
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/172174]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Kang, Guodong; Cao, Yiming
作者单位	1.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy DNL, Dalian 116023, Peoples R China
推荐引用方式 GB/T 7714	Zhu, Zhihao,Kang, Guodong,Sun, Ying,et al. An experimental study on synthesis of glycolic acid via carbonylation of formaldehyde using PTFE membrane contactor[J]. JOURNAL OF MEMBRANE SCIENCE,2019,586:259-266.
APA	Zhu, Zhihao.,Kang, Guodong.,Sun, Ying.,Yu, Sha.,Li, Meng.,...&Cao, Yiming.(2019).An experimental study on synthesis of glycolic acid via carbonylation of formaldehyde using PTFE membrane contactor.JOURNAL OF MEMBRANE SCIENCE,586,259-266.
MLA	Zhu, Zhihao,et al."An experimental study on synthesis of glycolic acid via carbonylation of formaldehyde using PTFE membrane contactor".JOURNAL OF MEMBRANE SCIENCE 586(2019):259-266.