Syntheses, structures and physical properties of transition metal-organic frameworks assembled from trigonal heterofunctional ligands

	Syntheses, structures and physical properties of transition metal-organic frameworks assembled from trigonal heterofunctional ligands
	Song SY ; Song XZ ; Zhao SN ; Qin C ; Su SQ ; Zhu M ; Hao ZM ; Zhang HJ
刊名	dalton transactions
	2012
卷号	41 期号:34 页码:10412-10421
关键词	COORDINATION POLYMERS ISOPHTHALIC ACID ROOM-TEMPERATURE DRUG-DELIVERY COMPLEXES CATALYSIS LUMINESCENCE SEPARATION COLIGANDS POROSITY
ISSN号	1477-9226
通讯作者	zhang hj
中文摘要	six novel metal-organic frameworks (mofs), {mn(bpydb)(bpyhdbh)}(n) (1) {[co-2(bpydb)(2)](h2o)(0.5)}(n) (2), {[ni-0.5(bpydbh)(h2o)](dmf)(2)}(n) (3), {[cu-2(bpydb)(2)](h2o)(0.5)}(n) (4), {zn(bpyhdb)(2)}(n) (5) and {[cd-0.5(bpydb)(0.5)(dmf)](h2o)}(n) (6), were successfully synthesized by assembling transition metal salts with trigonal heterofunctional ligand 4,4'-(4,4'-bipyridine-2,6-diyl) dibenzoic acid (bpydbh(2)) under hydrothermal and/or solvothermal conditions. compound 1 features a rare 4-fold interpenetrating (3,5)-connected framework with hms-type topology. isostructural compounds 2 and 4, constructed by m-2(coo)(4) secondary building units, exhibit a robust 3d framework with alb topological type in 2-fold interpenetrating mode. compound 3 consists of 2d (4,4) networks, which are further assembled into the new topological framework with the symbol (5(3).6(2).8)(5(3).6(3))(2) through o-h center dot center dot center dot o interactions. compound 5 manifests a novel 4-connected interpenetrating framework, constructed by 2d (4,4) layers and interbedded n-h center dot center dot center dot o interactions. non-interpenetrating honeycomb networks are observed in compound 6, and further packed into a 3d framework featuring 1d channels. the magnetic susceptibility of compound 2 indicates antiferromagnetic interactions between cobalt ions. the photoluminescent properties of 5 and 6 were investigated in the solid state at room temperature.
收录类别	SCI收录期刊论文
语种	英语
WOS记录号	WOS:000307306400036
公开日期	2013-06-30
内容类型	期刊论文
源URL	[http://ir.ciac.jl.cn/handle/322003/48494]
专题	长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式 GB/T 7714	Song SY,Song XZ,Zhao SN,et al. Syntheses, structures and physical properties of transition metal-organic frameworks assembled from trigonal heterofunctional ligands[J]. dalton transactions,2012,41(34):10412-10421.
APA	Song SY.,Song XZ.,Zhao SN.,Qin C.,Su SQ.,...&Zhang HJ.(2012).Syntheses, structures and physical properties of transition metal-organic frameworks assembled from trigonal heterofunctional ligands.dalton transactions,41(34),10412-10421.
MLA	Song SY,et al."Syntheses, structures and physical properties of transition metal-organic frameworks assembled from trigonal heterofunctional ligands".dalton transactions 41.34(2012):10412-10421.