Energy structure and fluorescence of Eu2+ in ZnS : Eu nanoparticles | |
Liu SM | |
刊名 | physical review b |
2000 | |
卷号 | 61期号:16页码:11021-11024 |
关键词 | PHOTOLUMINESCENCE CRYSTALLITES |
ISSN号 | 1098-0121 |
通讯作者 | chen w,nomad inc,1730 cimarron plaza,pob 2496,stillwater,ok 74076 usa. |
中文摘要 | eu2+-doped zns nanoparticles with an average size of around 3 nm were prepared, and an emission band around 530 nm was observed. by heating in air at 150 degrees c, this emission decreased, while the typical sharp line emission of eu3+ increased. this suggests that the emission around 530 nm is from intraion transition of eu2+: in bulk zns:eu2+, no intraion transition of eu2+ was observed because the excited states of eu2+ are degenerate with the continuum of the zns conduction band. we show that the band gap in zns:eu2+ nanoparticles opens up due to quantum confinement, such that the conduction band of zns is higher than the first excited state of eu2+, thus enabling the intraion transition of eu2+ to occur. |
学科主题 | 半导体物理 |
收录类别 | SCI |
语种 | 英语 |
公开日期 | 2010-08-12 |
内容类型 | 期刊论文 |
源URL | [http://ir.semi.ac.cn/handle/172111/12618] |
专题 | 半导体研究所_中国科学院半导体研究所(2009年前) |
推荐引用方式 GB/T 7714 | Liu SM. Energy structure and fluorescence of Eu2+ in ZnS : Eu nanoparticles[J]. physical review b,2000,61(16):11021-11024. |
APA | Liu SM.(2000).Energy structure and fluorescence of Eu2+ in ZnS : Eu nanoparticles.physical review b,61(16),11021-11024. |
MLA | Liu SM."Energy structure and fluorescence of Eu2+ in ZnS : Eu nanoparticles".physical review b 61.16(2000):11021-11024. |
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