Modulating the magnetic relaxation of lanthanide-based single-molecule magnets

	Modulating the magnetic relaxation of lanthanide-based single-molecule magnets
	Zhang P ; Zhang L ; Xue SF ; Lin SY ; Tang JK
刊名	chinese science bulletin
	2012
卷号	57 期号:20 页码:2517-2524
关键词	ANISOTROPIC BARRIER DY-3 TRIANGLES HIGH-SPIN COMPLEXES BEHAVIOR LIGAND CLUSTER EXCHANGE SURFACE STATES
ISSN号	1001-6538
通讯作者	tang jk
中文摘要	in the area of molecular magnetism, single molecule magnets (smms) containing lanthanide elements are of immense scientific and technological interest because of their large energy barriers and high measured hysteresis temperature. although there has been significant progress in the synthesis and characterization of lanthanide-based smms, there are still challenges, for instance, how single-ion anisotropy of lanthanide elements can be exploited, and how zero-field tunneling of magnetization can be suppressed. this article is devoted to the progress in various methodologies for modulating magnetic relaxation, especially in terms of crystal field and magnetic interactions. the crystal field plays a dominant role in creating single-molecule magnets with largely anisotropic f-elements, while the strong coupling between magnetic centers is able to suppress quantum tunneling of magnetization efficiently.
收录类别	SCI收录期刊论文
语种	英语
WOS记录号	WOS:000305916000003
公开日期	2013-05-20
内容类型	期刊论文
源URL	[http://ir.ciac.jl.cn/handle/322003/48070]
专题	长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式 GB/T 7714	Zhang P,Zhang L,Xue SF,et al. Modulating the magnetic relaxation of lanthanide-based single-molecule magnets[J]. chinese science bulletin,2012,57(20):2517-2524.
APA	Zhang P,Zhang L,Xue SF,Lin SY,&Tang JK.(2012).Modulating the magnetic relaxation of lanthanide-based single-molecule magnets.chinese science bulletin,57(20),2517-2524.
MLA	Zhang P,et al."Modulating the magnetic relaxation of lanthanide-based single-molecule magnets".chinese science bulletin 57.20(2012):2517-2524.