Mn(2,2'-bipy)(2)S-6 (n): A homochiral hybrid of manganese polysulfido compound with a one-dimensional Mn-S-6-Mn helical chain

	Mn(2,2'-bipy)(2)S-6 (n): A homochiral hybrid of manganese polysulfido compound with a one-dimensional Mn-S-6-Mn helical chain
	M. L. Fu ; G. C. Guo ; X. Liu ; J. P. Zou ; G. Xu ; J. S. Huang
刊名	Crystal Growth & Design
	2007-12
卷号	7 期号:12 页码:2387-2389
关键词	transition-metal-complexes chiral-symmetry-breaking capped cds clusters coordination polymers crystal-structure structural-characterization spontaneous resolution zintl anions solid-state crystallization
ISSN号	1528-7483
中文摘要	A novel manganese polysulfido hybrid, [Mn(2,2'-bipy)(2)S-6](n), which is the first example with Q(n)(2-) (Q = S, Se, Te, n >= 1) as a bridging ligand connecting metal atoms to form a one-dimensional helical chain, has been synthesized and structurally characterized. The compound exhibits semiconducting properties (E-g = 1.67 eV) and strong blue photoluminescence with the emission maximum occurring around 400 nm, and the variable-temperature magnetic susceptibility data suggest a weak antiferromagnetic interaction among Mn2+ ions in the compound.
语种	英语
公开日期	2013-04-01
内容类型	期刊论文
源URL	[http://ir.fjirsm.ac.cn/handle/350002/6245]
专题	福建物质结构研究所_中科院福建物质结构研究所_期刊论文
推荐引用方式 GB/T 7714	M. L. Fu,G. C. Guo,X. Liu,et al. Mn(2,2'-bipy)(2)S-6 (n): A homochiral hybrid of manganese polysulfido compound with a one-dimensional Mn-S-6-Mn helical chain[J]. Crystal Growth & Design,2007,7(12):2387-2389.
APA	M. L. Fu,G. C. Guo,X. Liu,J. P. Zou,G. Xu,&J. S. Huang.(2007).Mn(2,2'-bipy)(2)S-6 (n): A homochiral hybrid of manganese polysulfido compound with a one-dimensional Mn-S-6-Mn helical chain.Crystal Growth & Design,7(12),2387-2389.
MLA	M. L. Fu,et al."Mn(2,2'-bipy)(2)S-6 (n): A homochiral hybrid of manganese polysulfido compound with a one-dimensional Mn-S-6-Mn helical chain".Crystal Growth & Design 7.12(2007):2387-2389.