{Ln(III) mu(5)-K-2,K-1,K-1,K-1,K-1-1,2-(CO2)(2)C6H4 isonicotine H2O }( 2)Cu-I center dot X (Ln = eu, sm, nd; x = ClO4-, Cl-): A new pillared-layer approach to heterobimetallic 3d-4f 3D-Network solids

	{Ln(III) mu(5)-K-2,K-1,K-1,K-1,K-1-1,2-(CO2)(2)C6H4 isonicotine H2O }( 2)Cu-I center dot X (Ln = eu, sm, nd; x = ClO4-, Cl-): A new pillared-layer approach to heterobimetallic 3d-4f 3D-Network solids
	J. W. Cheng ; S. T. Zheng ; E. Ma ; G. Y. Yang
刊名	Inorganic Chemistry
	2007-12
卷号	46 期号:25 页码:10534-10538
关键词	metal-organic frameworks coordination polymers hydrothermal synthesis crystal-structure hydrogen storage lanthanide ions design complexes linkages sorption
ISSN号	0020-1669
中文摘要	A new series of heterometallic lanthanide(III)-copper(I) coordination polymers Ln(2)(bdc)(2)(ina)(2)(H2O)(2)CU center dot X (Hina = isonicotinic acid; H(2)bdc = 1,2-benzenedicarboxylic acid; Ln = Eu (1), Sm (2), Nd (3), X = ClO4-; Ln = Nd (4), X = Cl-) have been hydrothermally synthesized in the presence/absence of HClO4. Both compounds are isostructural and contained two distinct units of 2D Ln-bdc layers and linear [Cu(ina)(2)](-). The linear [Cu(ina)21- complexes act as pillars and further link the Ln-bdc layers resulting in four heterometallic metal-organic frameworks, which represent the first pillared-layer 3d-4f framework with two distinct types of channels along the b and c axes. The compounds can be specified by. the Schlafli symbol (4(7 center dot)6(3))(4(7)center dot 6(8)) as a novel 3D (5,6)-connected net. Furthermore, the IR, TGA, PXRD, and UV-vis spectral and luminescent properties of 1-4 were also studied.
语种	英语
公开日期	2013-04-01
内容类型	期刊论文
源URL	[http://ir.fjirsm.ac.cn/handle/350002/6196]
专题	福建物质结构研究所_中科院福建物质结构研究所_期刊论文
推荐引用方式 GB/T 7714	J. W. Cheng,S. T. Zheng,E. Ma,et al. {Ln(III) mu(5)-K-2,K-1,K-1,K-1,K-1-1,2-(CO2)(2)C6H4 isonicotine H2O }( 2)Cu-I center dot X (Ln = eu, sm, nd; x = ClO4-, Cl-): A new pillared-layer approach to heterobimetallic 3d-4f 3D-Network solids[J]. Inorganic Chemistry,2007,46(25):10534-10538.
APA	J. W. Cheng,S. T. Zheng,E. Ma,&G. Y. Yang.(2007).{Ln(III) mu(5)-K-2,K-1,K-1,K-1,K-1-1,2-(CO2)(2)C6H4 isonicotine H2O }( 2)Cu-I center dot X (Ln = eu, sm, nd; x = ClO4-, Cl-): A new pillared-layer approach to heterobimetallic 3d-4f 3D-Network solids.Inorganic Chemistry,46(25),10534-10538.
MLA	J. W. Cheng,et al."{Ln(III) mu(5)-K-2,K-1,K-1,K-1,K-1-1,2-(CO2)(2)C6H4 isonicotine H2O }( 2)Cu-I center dot X (Ln = eu, sm, nd; x = ClO4-, Cl-): A new pillared-layer approach to heterobimetallic 3d-4f 3D-Network solids".Inorganic Chemistry 46.25(2007):10534-10538.