Synthesis and properties of novel poly(benzimidazopyrrolone amide)s containing pyridine moieties

CORC > 兰州化学物理研究所 > 中国科学院兰州化学物理研究所 > 固体润滑国家重点实验室

	Synthesis and properties of novel poly(benzimidazopyrrolone amide)s containing pyridine moieties
	Wang XL(王晓龙)
刊名	Journal of Applied Polymer Science
	2008
卷号	109 页码:3369-3375
关键词	heteroatom-containing polymers high-performance polymers thermal properties
ISSN号	0021-8995
通讯作者	李彦峰
中文摘要	A series of new poly(benzimidazopyrrolone amide) (PPA) copolymers were synthesized by a two-step procedure, which was the solution polycondensation of a novel pyridine-containing tetraamine with various aromatic dianhydrides at a room temperature and cyclization of the resulting prepolymers at a high temperature, respectively. The resulting prepolymers from the solution polycondensation, that is, poly(amide amino acid)s (PAAAs), had inherent viscosities of 0.82–0.91 dL/g; then, tough and flexible PPA films could be successfully prepared by the casting of the PAAA solutions onto a glass substrate followed by thermal curing with a program temperature procedure up to 350℃. The obtained PPA films exhibited not only excellent thermal properties with onset decomposition temperatures in the range 502–521℃, glass-transition temperatures in the range 299–337℃, and residual weight retentions at 700℃ in air of 29.1–34.8% but also good mechanical properties with tensile strengths of 102.1–115.9 MPa and elongations at break of 6.8–7.4%.
学科主题	材料科学与物理化学
收录类别	SCI
资助信息	Research Foundation of the State Key Laboratory of Applied Organic Chemistry
语种	英语
WOS记录号	WOS:000257442900081
公开日期	2013-03-28
内容类型	期刊论文
源URL	[http://210.77.64.217/handle/362003/2619]
专题	兰州化学物理研究所_固体润滑国家重点实验室
推荐引用方式 GB/T 7714	Wang XL. Synthesis and properties of novel poly(benzimidazopyrrolone amide)s containing pyridine moieties[J]. Journal of Applied Polymer Science,2008,109:3369-3375.
APA	王晓龙.(2008).Synthesis and properties of novel poly(benzimidazopyrrolone amide)s containing pyridine moieties.Journal of Applied Polymer Science,109,3369-3375.
MLA	王晓龙."Synthesis and properties of novel poly(benzimidazopyrrolone amide)s containing pyridine moieties".Journal of Applied Polymer Science 109(2008):3369-3375.