A novel tin-bismuth alloy electrode for anodic stripping voltammetric determination of zinc

CORC > 烟台海岸带研究所 > 中国科学院烟台海岸带研究所 > 中科院海岸带环境过程与生态修复重点实验室

	A novel tin-bismuth alloy electrode for anodic stripping voltammetric determination of zinc
	Pan, Dawei1 ; Zhang, Li 1,2; Zhuang, Jianmei 3; Yin, Tanji1 ; Qin, Wei1
刊名	MICROCHIMICA ACTA
	2012-04-01
卷号	177 期号:1-2 页码:59-66
关键词	Tin-bismuth alloy electrode Anodic stripping voltammetry Zinc Wine Honey
ISSN号	0026-3672
通讯作者	Pan, DW (reprint author), Chinese Acad Sci, Yantai Inst Coastal Zone Res, Shandong Prov Key Lab Coastal Zone Environm Proc, Yantai 264003, Peoples R China.,dwpan@yic.ac.cn
产权排序	[Pan, Dawei; Zhang, Li; Yin, Tanji; Qin, Wei] Chinese Acad Sci, Yantai Inst Coastal Zone Res, Shandong Prov Key Lab Coastal Zone Environm Proc, Yantai 264003, Peoples R China; [Zhang, Li] Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China; [Zhuang, Jianmei] Shandong Normal Univ, Key Lab Mol & Nanomat Probes, Minist Educ China, Coll Chem Chem Engn & Mat Sci, Jinan 250014, Peoples R China
中文摘要	We report on a novel tin-bismuth alloy electrode (SnBiE) for the determination of trace concentrations of zinc ions by square-wave anodic stripping voltammetry without deoxygenation. The SnBiE has the advantages of easy fabrication and low cost, and does not require a pre-treatment (in terms of modification) prior to measurements. A study on the potential window of the electrode revealed a high hydrogen overvoltage though a limited anodic range due to the oxidation of tin. The effects of pH value, accumulation potential, and accumulation time were optimized with respect to the determination of trace zinc(II) at pH 5.0. The response of the SnBiE to zinc(II) ion is linear in the 0.5-25 mu M concentration range. The detection limit is 50 nM (after 60 s of accumulation). The SnBiE was applied to the determination of zinc(II) in wines and honeys, and the results were consistent with those of AAS.
英文摘要	We report on a novel tin-bismuth alloy electrode (SnBiE) for the determination of trace concentrations of zinc ions by square-wave anodic stripping voltammetry without deoxygenation. The SnBiE has the advantages of easy fabrication and low cost, and does not require a pre-treatment (in terms of modification) prior to measurements. A study on the potential window of the electrode revealed a high hydrogen overvoltage though a limited anodic range due to the oxidation of tin. The effects of pH value, accumulation potential, and accumulation time were optimized with respect to the determination of trace zinc(II) at pH 5.0. The response of the SnBiE to zinc(II) ion is linear in the 0.5-25 mu M concentration range. The detection limit is 50 nM (after 60 s of accumulation). The SnBiE was applied to the determination of zinc(II) in wines and honeys, and the results were consistent with those of AAS.
学科主题	Chemistry, Analytical
研究领域[WOS]	Chemistry
关键词[WOS]	GLASSY-CARBON ELECTRODES ; FILM ELECTRODES ; BULK ELECTRODE ; HEAVY-METALS ; TRACE-METALS ; MERCURY ; LEAD ; CADMIUM ; IONS ; ZN
收录类别	SCI
资助信息	National Natural Science Foundation of China[21007087]; Chinese Academy of Sciences[KZCX2-YW-JS208]; Natural Science Foundation of Shandong Province[2008ZRA06004, BS2010HZ030]; Science and Technology Development Project of Yantai City[2009164]; Taishan Scholar Program of Shandong Province; Youth Innovation Promotion Association of CAS
语种	英语
WOS记录号	WOS:000304134700007
公开日期	2013-03-08
内容类型	期刊论文
源URL	[http://ir.yic.ac.cn/handle/133337/5953]
专题	烟台海岸带研究所_中科院海岸带环境过程与生态修复重点实验室
作者单位	1.Chinese Acad Sci, Yantai Inst Coastal Zone Res, Shandong Prov Key Lab Coastal Zone Environm Proc, Yantai 264003, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China 3.Shandong Normal Univ, Key Lab Mol & Nanomat Probes, Minist Educ China, Coll Chem Chem Engn & Mat Sci, Jinan 250014, Peoples R China
推荐引用方式 GB/T 7714	Pan, Dawei,Zhang, Li,Zhuang, Jianmei,et al. A novel tin-bismuth alloy electrode for anodic stripping voltammetric determination of zinc[J]. MICROCHIMICA ACTA,2012,177(1-2):59-66.
APA	Pan, Dawei,Zhang, Li,Zhuang, Jianmei,Yin, Tanji,&Qin, Wei.(2012).A novel tin-bismuth alloy electrode for anodic stripping voltammetric determination of zinc.MICROCHIMICA ACTA,177(1-2),59-66.
MLA	Pan, Dawei,et al."A novel tin-bismuth alloy electrode for anodic stripping voltammetric determination of zinc".MICROCHIMICA ACTA 177.1-2(2012):59-66.