Convenient Synthesis of Thermo-Responsive PtBA-g-PPEGMEMA Well-Defined Amphiphilic Graft Copolymer Without Polymeric Functional Group Transformation | |
Song XM(宋学梅) ; Zhang YQ(张亚琴) ; Yang D(杨东) ; Yuan L(袁丽) ; Hu JH(胡建华) ; Lu GL(陆国林) ; Huang XY(黄晓宇) | |
刊名 | J. Polym. Sci. Pol. Chem. |
2011 | |
卷号 | 49期号:15页码:3328-3337 |
ISSN号 | 0887-624X |
其他题名 | 无聚合物官能团转变的热敏性结构规整的PtBA-g-PPEGMEMA两亲性接枝共聚物的便捷合成 |
通讯作者 | 胡建华 ; 黄晓宇 |
英文摘要 | A series of well-defined amphiphilic graft copolymers bearing hydrophobic poly(tert-butyl acrylate) backbone and hydrophilic poly[poly(ethylene glycol) methyl ether methacrylate)] (PPEGMEMA) side chains were synthesized by sequential reversible addition fragmentation chain transfer (RAFT) polymerization and single-electron-transfer living radical polymerization (SET-LRP) without any polymeric functional group transformation. A new Br-containing acrylate monomer, tert-butyl 2-((2-bromoisobutanoyloxy)methyl)acrylate (tBBIBMA), was first prepared, which can be homopolymerized by RAFT to give a well-defined PtBBIBMA homopolymer with a narrow molecular weight distribution (M(w)/M(n) 1.15). This homopolymer with pendant Br initiation group in every repeating unit initiated SET-LRP of PEGMEMA at 45 degrees C using CuBr/dHbpy as catalytic system to afford well-defined PtBBIBMA-g-PPEGMEMA graft copolymers via the grafting-from strategy. The self-assembly behavior of the obtained graft copolymers in aqueous media was investigated by fluorescence spectroscopy and TEM. These copolymers were found to be stimuli-responsive to both temperature and ions. Finally, poly(acrylic acid)-g-PPEGMEMA double hydrophilic graft copolymers were obtained by selective acidic hydrolysis of hydrophobic PtBA backbone while PPEGMEMA side chains kept inert. (C) 2011 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 49: 3328-3337, 2011 |
学科主题 | 高分子化学 |
收录类别 | SCI |
原文出处 | http://dx.doi.org/10.1002/pola.24769 |
语种 | 英语 |
WOS记录号 | WOS:000293279500010 |
公开日期 | 2013-03-11 |
内容类型 | 期刊论文 |
源URL | [http://202.127.28.38/handle/331003/24445] |
专题 | 上海有机化学研究所_高分子材料研究室 |
推荐引用方式 GB/T 7714 | Song XM,Zhang YQ,Yang D,et al. Convenient Synthesis of Thermo-Responsive PtBA-g-PPEGMEMA Well-Defined Amphiphilic Graft Copolymer Without Polymeric Functional Group Transformation[J]. J. Polym. Sci. Pol. Chem.,2011,49(15):3328-3337. |
APA | 宋学梅.,张亚琴.,杨东.,袁丽.,胡建华.,...&黄晓宇.(2011).Convenient Synthesis of Thermo-Responsive PtBA-g-PPEGMEMA Well-Defined Amphiphilic Graft Copolymer Without Polymeric Functional Group Transformation.J. Polym. Sci. Pol. Chem.,49(15),3328-3337. |
MLA | 宋学梅,et al."Convenient Synthesis of Thermo-Responsive PtBA-g-PPEGMEMA Well-Defined Amphiphilic Graft Copolymer Without Polymeric Functional Group Transformation".J. Polym. Sci. Pol. Chem. 49.15(2011):3328-3337. |
个性服务 |
查看访问统计 |
相关权益政策 |
暂无数据 |
收藏/分享 |
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。
修改评论