Grignard reagent induced tandem semipinacol rearrangement/ketone addition reaction of 20S-hydroxy-5 alpha-pregnane-16(17)-epoxide

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	Grignard reagent induced tandem semipinacol rearrangement/ketone addition reaction of 20S-hydroxy-5 alpha-pregnane-16(17)-epoxide
	Huang CX(黄春希) ; Shi Y(史勇) ; Lin JR(林静容) ; Jin RH(金荣华) ; Tian WS(田伟生)
刊名	Tetrahedron Lett.
	2011
卷号	52 期号:32 页码:4123-4125
ISSN号	0040-4039
其他题名	一个由Grignard 试剂引发的semipinacol重排, 加成反应
通讯作者	田伟生
英文摘要	A Grignard reagent induced tandem semipinacol rearrangement/chelation-controlled ketone addition process, which converts 20S-hydroxy-5 alpha-pregnane-16(17)-epoxide into an unusual C20-substituted 17S-pregnane-3S,16R,20S-triol, is described. (C) 2011 Elsevier Ltd. All rights reserved.
学科主题	有机化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1016/j.tetlet.2011.05.122
语种	英语
WOS记录号	WOS:000293321000016
公开日期	2013-03-11
内容类型	期刊论文
源URL	[http://202.127.28.38/handle/331003/23886]
专题	上海有机化学研究所_中科院天然产物有机化学重点实验室
推荐引用方式 GB/T 7714	Huang CX,Shi Y,Lin JR,et al. Grignard reagent induced tandem semipinacol rearrangement/ketone addition reaction of 20S-hydroxy-5 alpha-pregnane-16(17)-epoxide[J]. Tetrahedron Lett.,2011,52(32):4123-4125.
APA	黄春希,史勇,林静容,金荣华,&田伟生.(2011).Grignard reagent induced tandem semipinacol rearrangement/ketone addition reaction of 20S-hydroxy-5 alpha-pregnane-16(17)-epoxide.Tetrahedron Lett.,52(32),4123-4125.
MLA	黄春希,et al."Grignard reagent induced tandem semipinacol rearrangement/ketone addition reaction of 20S-hydroxy-5 alpha-pregnane-16(17)-epoxide".Tetrahedron Lett. 52.32(2011):4123-4125.