Supramolecular assemblies of (+/-)-2,2 '-dihydroxy-1,1 '-binaphthyl with 2,2 '-bipyridine and naphthodiazine | |
Ji BM(吉保明) ; Chen HT(陈花婷) ; Du CX(杜晨霞) ; Ding KL(丁奎岭) | |
刊名 | Chin. J. Chem.
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2004 | |
卷号 | 22期号:9页码:1045-1051 |
ISSN号 | 1001-604X |
其他题名 | 外消旋BINOL与2,2‘-联吡啶和吩嗪的超分子组装体结构研究 |
通讯作者 | 吉保明 ; 丁奎岭 |
英文摘要 | Supramolecular assemblies of (+/-)-2,2'-dihydroxy-1,1'-binaphthyl (BINOL, A), with aza donor molecules including 2,2'-bipyridine (B) and naphthodiazine (C), have been synthesized and characterized by single-crystal X-ray diffraction methods. Two inclusion complexes crystallize in the triclinic system with P-1 space group. In the inclusion complex between A and B, two molecules of A and two molecules of B are linked each other by intermolecular hydrogen bonds with two molecules of water as the bridges, forming a centrosymmetric dimer with formula of A(2)(H2O)(2)B-2; while in the inclusion complex between A and C, the molecule C virtually acts as a bridge to link molecules A through intermolecular O-H...N hydrogen bonds, forming a short-chain supramolecular block with a formula of A(2).C-3. Besides the hydrogen bonding interaction between the host and guest molecules, pi-pi stacking interactions also play an important role in the solid-state packing of these two inclusion complexes. The structural information disclosed on the complex between dihydroxy compound and aza hydrogen bond acceptors in this work would be particularly important for the rational design of supramolecular organic functional materials. |
学科主题 | 有机化学 |
收录类别 | SCI |
原文出处 | http://dx.doi.org/10.1002/cjoc.20040220933 |
语种 | 英语 |
WOS记录号 | WOS:000223842000033 |
公开日期 | 2013-02-22 |
内容类型 | 期刊论文 |
源URL | [http://202.127.28.38/handle/331003/17767] ![]() |
专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
推荐引用方式 GB/T 7714 | Ji BM,Chen HT,Du CX,et al. Supramolecular assemblies of (+/-)-2,2 '-dihydroxy-1,1 '-binaphthyl with 2,2 '-bipyridine and naphthodiazine[J]. Chin. J. Chem.,2004,22(9):1045-1051. |
APA | 吉保明,陈花婷,杜晨霞,&丁奎岭.(2004).Supramolecular assemblies of (+/-)-2,2 '-dihydroxy-1,1 '-binaphthyl with 2,2 '-bipyridine and naphthodiazine.Chin. J. Chem.,22(9),1045-1051. |
MLA | 吉保明,et al."Supramolecular assemblies of (+/-)-2,2 '-dihydroxy-1,1 '-binaphthyl with 2,2 '-bipyridine and naphthodiazine".Chin. J. Chem. 22.9(2004):1045-1051. |
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