Titanium(IV) chloride and the amine-promoted baylis-hillman reaction | |
Shi M(施敏) ; Jiang JK(蒋建康) ; Feng YS(冯言枢) | |
刊名 | Org. Lett. |
2000 | |
卷号 | 2期号:16页码:2397-2400 |
其他题名 | Ticl4和胺类化合物促进的Baylis-Hillman反应 |
通讯作者 | 施敏 |
英文摘要 | In the baylis0hillman reaction, we found that, when the reactions of aryladehydes with methyl vinyl ketone were carried out at ←20℃ using a catalytic amount of amine as a lewis base in the presence of titanium(IV)chloride, the chlorinated compounds 1 could be obtained as the major product invery high yields for various arylaldehydes. In addition, acrylonitrile could undergo the same reaction to give the corresponding chlorinated product in moderate yield./* |
学科主题 | 金属有机化学 |
收录类别 | SCI |
原文出处 | http://dx.doi.org/10.1021/ol000046x |
语种 | 英语 |
WOS记录号 | WOS:000088605200002 |
公开日期 | 2013-01-09 |
内容类型 | 期刊论文 |
源URL | [http://202.127.28.38/handle/331003/9722] |
专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
推荐引用方式 GB/T 7714 | Shi M,Jiang JK,Feng YS. Titanium(IV) chloride and the amine-promoted baylis-hillman reaction[J]. Org. Lett.,2000,2(16):2397-2400. |
APA | Shi M,Jiang JK,&Feng YS.(2000).Titanium(IV) chloride and the amine-promoted baylis-hillman reaction.Org. Lett.,2(16),2397-2400. |
MLA | Shi M,et al."Titanium(IV) chloride and the amine-promoted baylis-hillman reaction".Org. Lett. 2.16(2000):2397-2400. |
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