Tunable Coordinative Assembly of a Disc-Like Molecule and Metal Ions: From Mirospheres to Microtubes and Microrods

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	Tunable Coordinative Assembly of a Disc-Like Molecule and Metal Ions: From Mirospheres to Microtubes and Microrods
	Xiao ZY(肖泽云) ; Zhao X(赵新) ; Jiang XK(蒋锡夔) ; Li ZT(黎占亭)
刊名	Chem. Mat.
	2011
卷号	23 期号:6 页码:1505-1511
ISSN号	0897-4756
其他题名	配位作用驱动的盘状分子与金属离子可调控组装: 从微米球、微米管到微米棒
通讯作者	赵新 ; 黎占亭
英文摘要	This study reports a tunable metallo-supramolecular assembly strategy to construct microscaled objects with different morphologies. Three well-defined discrete microstructures-microspheres, macrotubes, and microrods-have been fabricated through metal-organic coordination between the same organic unit and different transition metal ions or the same organic unit and metal ion processed in different solvents. The formations of microspheres, microtubes, and microrods have been readily evidenced by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). Encapsulation experiments revealed that those microspheres could entrap rhodamine B and might be used as carrier materials. It was also found that the microrods and microtubes could be transformed into each other by adding or removing water to or from the solution. The formation mechanisms of these microstructures have also been discussed on the basis of spectroscopic and crystallographic studies.
学科主题	物理有机化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1021/cm103182e
语种	英语
WOS记录号	WOS:000288291400022
公开日期	2013-01-16
内容类型	期刊论文
源URL	[http://202.127.28.38/handle/331003/12768]
专题	上海有机化学研究所_物理有机化学研究室
推荐引用方式 GB/T 7714	Xiao ZY,Zhao X,Jiang XK,et al. Tunable Coordinative Assembly of a Disc-Like Molecule and Metal Ions: From Mirospheres to Microtubes and Microrods[J]. Chem. Mat.,2011,23(6):1505-1511.
APA	肖泽云,赵新,蒋锡夔,&黎占亭.(2011).Tunable Coordinative Assembly of a Disc-Like Molecule and Metal Ions: From Mirospheres to Microtubes and Microrods.Chem. Mat.,23(6),1505-1511.
MLA	肖泽云,et al."Tunable Coordinative Assembly of a Disc-Like Molecule and Metal Ions: From Mirospheres to Microtubes and Microrods".Chem. Mat. 23.6(2011):1505-1511.