Semiorganic Nonlinear Optical Material: Preparation and Properties of (NH4)center dot Sr[L-(+)-C4H2O6 center dot B(OH)(2)]center dot 4H(2)O

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	Semiorganic Nonlinear Optical Material: Preparation and Properties of (NH4)center dot Sr[L-(+)-C4H2O6 center dot B(OH)(2)]center dot 4H(2)O
	Fan Xiaoyun; Pan Shilie; Hou Xueling; Liu Gang; Wang Jide
刊名	INORGANIC CHEMISTRY
	2009
卷号	48 期号:11 页码:4806-4810
ISSN号	0020-1669
通讯作者	Pan, SL
英文摘要	The synthesis, crystal structure, and characterization of the noncentrosymmetric semiorganic material (NH4)center dot SrL-(+)-C4H2O6 center dot B(OH)(2)center dot 4H(2)O were reported. Crystals were synthesized through slow evaporation at room temperature, utilizing SrCl2 center dot 6H(2)O, C4H4O6, H3BO3, and NH3, H2O as reagents, and its structure was determined by single-crystal X-ray diffraction. It crystallizes in the triclinic space group P1 (No. 1) with a=6.4633(10) angstrom, b=7.0452(13) angstrom, c = 7.0745(12) angstrom, alpha = 85.351(5), beta = 77.678(5), gamma = 73.276(4), and Z=1. It exhibits a two-dimensional layered structure along the c axis, consisting of SrO9 polyhedra, BO4 tetrahedra, tartrate molecules, NH4 cations, and H2O molecules. IR spectroscopy, UV-vis diffuse-reflectance spectroscopy, thermal analysis, and second-harmonic generation (SHG) were also performed on the reported material. Nonlinear optical measurements, using 1064 nm radiation, indicate that the material has SHG properties, with an efficiency of approximately 1.5 times that of KH2PO4.
学科主题	Chemistry
收录类别	SCI
WOS记录号	WOS:000266428100041
公开日期	2012-11-29
内容类型	期刊论文
源URL	[http://ir.xjipc.cas.cn/handle/365002/1886]
专题	新疆理化技术研究所_材料物理与化学研究室新疆理化技术研究所_资源化学研究室
作者单位	Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China; Xinjiang Univ, Coll Chem & Chem Engn, Urumqi 830046, Peoples R China
推荐引用方式 GB/T 7714	Fan Xiaoyun,Pan Shilie,Hou Xueling,et al. Semiorganic Nonlinear Optical Material: Preparation and Properties of (NH4)center dot Sr[L-(+)-C4H2O6 center dot B(OH)(2)]center dot 4H(2)O[J]. INORGANIC CHEMISTRY,2009,48(11):4806-4810.
APA	Fan Xiaoyun,Pan Shilie,Hou Xueling,Liu Gang,&Wang Jide.(2009).Semiorganic Nonlinear Optical Material: Preparation and Properties of (NH4)center dot Sr[L-(+)-C4H2O6 center dot B(OH)(2)]center dot 4H(2)O.INORGANIC CHEMISTRY,48(11),4806-4810.
MLA	Fan Xiaoyun,et al."Semiorganic Nonlinear Optical Material: Preparation and Properties of (NH4)center dot Sr[L-(+)-C4H2O6 center dot B(OH)(2)]center dot 4H(2)O".INORGANIC CHEMISTRY 48.11(2009):4806-4810.