Non-centrosymmetric sodium borate: Crystal growth, characterization and properties on Na2B4O12H10
Wang Yongjiang; Pan Shilie; Hou Xueling; Liu Gang; Wang Jide; Jia Dianzeng
刊名Solid State Sciences
2010
卷号12期号:10页码:1726-1730
ISSN号12932558
通讯作者Pan, SL
中文摘要In this study, both solvent evaporation and hydrothermal methods were employed to grow hydrated sodium borate crystals using NaOH and H 3BO3 as reagents, and transparent and colorless single-crystals were successfully obtained with sizes up to 12 × 6 × 6 mm3 and 6 × 5 × 4 mm3, respectively. The structure is determined by single-crystal X-ray diffraction techniques. The title compound crystallizes in the trigonal space group R32, with a = 11.1042(16) , b = 11.1042(16) , c = 21.131(4) , Z = 9 and R1 = 0.0322, wR2 = 0.0840. Infrared and transmission spectra are presented for the reported material. The powder second-harmonic generation (SHG) intensity measured by the Kurtz-Perry method indicates that the SHG effect of Na2B4O12H10 is about one-third times that of KH2PO4 (KDP). © 2010 Elsevier Masson SAS. All rights reserved.
学科主题Chemistry ; Physics
公开日期2012-11-29
内容类型期刊论文
源URL[http://ir.xjipc.cas.cn/handle/365002/1853]  
专题新疆理化技术研究所_新疆维吾尔自治区电子信息材料与器件重点实验室
新疆理化技术研究所_资源化学研究室
作者单位Chinese Acad Sci, Xinjiang Key Lab Elect Informat Mat & Devices, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China;Xinjiang Univ, Coll Chem & Chem Engn, Urumqi 830046, Peoples R China
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Wang Yongjiang,Pan Shilie,Hou Xueling,et al. Non-centrosymmetric sodium borate: Crystal growth, characterization and properties on Na2B4O12H10[J]. Solid State Sciences,2010,12(10):1726-1730.
APA Wang Yongjiang,Pan Shilie,Hou Xueling,Liu Gang,Wang Jide,&Jia Dianzeng.(2010).Non-centrosymmetric sodium borate: Crystal growth, characterization and properties on Na2B4O12H10.Solid State Sciences,12(10),1726-1730.
MLA Wang Yongjiang,et al."Non-centrosymmetric sodium borate: Crystal growth, characterization and properties on Na2B4O12H10".Solid State Sciences 12.10(2010):1726-1730.
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