Synthesis, crystal structure and optical properties of a new lead bismuth borate

CORC > 新疆理化技术研究所 > 中国科学院新疆理化技术研究所 > 新疆维吾尔自治区电子信息材料与器件重点实验室

	Synthesis, crystal structure and optical properties of a new lead bismuth borate
	Zhao Wenwu; Pan Shilie; Han Jian; Zhou Zhongxiang
刊名	INORGANICA CHIMICA ACTA
	2011
卷号	379 期号:1 页码:130-134
关键词	PbBiBO(4) Powder synthesis Crystal structure UV-Vis-NIR Diffuse-Reflectance spectrum
ISSN号	0020-1693
通讯作者	Pan, SL
中文摘要	A new phase of the compound PbBiBO(4) has been successfully synthesized via the standard solid-state reaction, and the crystal structure has been determined from X-ray monocrystal diffraction data. It crystallizes in orthorhombic space group Cmca (No. 64) with lattice constants a = 10.782(3) angstrom, b = 10.502(3) angstrom, c = 7.477(2) angstrom, Z = 8. The crystal structure is characterized by a three-dimensional structure consisting of BiO(6) octahedra, PbO(4) tetrahedra and BO(3) triangles. The BiO(6) octahedra compose the layers through the O(2) atoms and O(3) atoms along the 101 direction, which connects the BO(3) trigonal groups by sharing the O(3) and two O(1) atoms and links the PbO(4) tetrahedra through the O(2) atoms. The UV-Vis-NIR Diffuse-Reflectance spectrum shows that the ultraviolet cutoff edge for the PbBiBO(4) crystal is about 310 nm. Functional groups in the sample were identified by Infrared spectrum.
学科主题	Chemistry
收录类别	SCI
资助信息	National Natural Science Foundation of China 50802110, 21001114; Chinese Academy of Sciences; Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry 20091001; Natural Science Foundation of Xinjiang Uygur Autonomous Region of China 200821159, 2009211B33; Xinjiang Uygur Autonomous Region of China 200816120
公开日期	2012-11-29
内容类型	期刊论文
源URL	[http://ir.xjipc.cas.cn/handle/365002/1650]
专题	新疆理化技术研究所_新疆维吾尔自治区电子信息材料与器件重点实验室
作者单位	Chinese Acad Sci, Xinjiang Key Lab Elect Informat Mat & Devices, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Zhao Wenwu,Pan Shilie,Han Jian,et al. Synthesis, crystal structure and optical properties of a new lead bismuth borate[J]. INORGANICA CHIMICA ACTA,2011,379(1):130-134.
APA	Zhao Wenwu,Pan Shilie,Han Jian,&Zhou Zhongxiang.(2011).Synthesis, crystal structure and optical properties of a new lead bismuth borate.INORGANICA CHIMICA ACTA,379(1),130-134.
MLA	Zhao Wenwu,et al."Synthesis, crystal structure and optical properties of a new lead bismuth borate".INORGANICA CHIMICA ACTA 379.1(2011):130-134.