Synthesis and crystal structure of a novel boratotungstate: Pb6B2WO12

CORC > 新疆理化技术研究所 > 中国科学院新疆理化技术研究所 > 新疆维吾尔自治区电子信息材料与器件重点实验室

	Synthesis and crystal structure of a novel boratotungstate: Pb6B2WO12
	Li Junjie; Pan Shilie; Zhao Wenwu; Tian Xuelin; Han Jian; Fan Xiaoyun
刊名	Solid State Sciences
	2011
卷号	13 期号:5 页码:966-969
关键词	Pb6B2WO12 Boratotungstate Structure determination Single-crystal diffraction
ISSN号	12932558
通讯作者	Pan, SL
英文摘要	A novel boratotungstate, Pb6B2WO12, has been prepared by solid-state reaction. The single-crystal X-ray structural analysis showed that Pb6B2WO12 crystallizes in the orthorhombic space group Cmcm (No. 63) with a = 18.4904(5) , b = 6.35980(10) , c = 11.6789(2) , Z = 4 and R1 = 0.0253, wR2 = 0.0557. The compound is characterized by one-dimensional (Pb3O)∞1 chains formed by corner-sharing OPb4 tetrahedra. BO3 and WO4 groups are located around the chains to hold them together via Pb-O bonds. The IR spectra further confirmed the presence of BO3 groups in the structure. The thermal analysis suggests that Pb6B2WO 12 is a congruently melting compound.
学科主题	Chemistry ; Physics
收录类别	SCI
公开日期	2012-11-29
内容类型	期刊论文
源URL	[http://ir.xjipc.cas.cn/handle/365002/1429]
专题	新疆理化技术研究所_新疆维吾尔自治区电子信息材料与器件重点实验室
作者单位	Chinese Acad Sci, Xinjiang Key Lab Elect Informat Mat & Devices, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
推荐引用方式 GB/T 7714	Li Junjie,Pan Shilie,Zhao Wenwu,et al. Synthesis and crystal structure of a novel boratotungstate: Pb6B2WO12[J]. Solid State Sciences,2011,13(5):966-969.
APA	Li Junjie,Pan Shilie,Zhao Wenwu,Tian Xuelin,Han Jian,&Fan Xiaoyun.(2011).Synthesis and crystal structure of a novel boratotungstate: Pb6B2WO12.Solid State Sciences,13(5),966-969.
MLA	Li Junjie,et al."Synthesis and crystal structure of a novel boratotungstate: Pb6B2WO12".Solid State Sciences 13.5(2011):966-969.