A New Lithium Rubidium Borate Li6Rb5B11O22 with Isolated B11O22 Building Blocks

CORC > 新疆理化技术研究所 > 中国科学院新疆理化技术研究所 > 新疆维吾尔自治区电子信息材料与器件重点实验室

	A New Lithium Rubidium Borate Li6Rb5B11O22 with Isolated B11O22 Building Blocks
	Yang Yun; Pan Shilie; Han Jian; Hou Xueling; Zhou Zhongxiang; Zhao Wenwu; Chen Zhaohui; Zhang Min
刊名	CRYSTAL GROWTH & DESIGN
	2011
卷号	11 期号:9 页码:3912-3916
ISSN号	15287483
通讯作者	Pan, SL
中文摘要	A new noncentrosymmetric polyborate, Li6Rb5B 11O22, has been designed and synthesized in the Li 2O-Rb2O-B2O3 ternary system. The structure of the title compound was solved by single crystal X-ray diffraction analysis. It crystallizes in the monoclinic space group C2. The new structure contains an infinite three-dimensional matrix that is built from B 11O22 building blocks and LiOn (n = 4, 5), RbOn (n = 9, 10) polyhedra. The B11O22 building block has not been reported previously in any anhydrous and hydrated borates. The optical characterization of the compound indicates that its UV cutoff edge is below 190 nm. IR spectroscopy, thermal analysis, and second-harmonic generation were also performed on the reported material.
学科主题	Chemistry ; Crystallography ; Materials Science
公开日期	2012-11-29
内容类型	期刊论文
源URL	[http://ir.xjipc.cas.cn/handle/365002/1413]
专题	新疆理化技术研究所_新疆维吾尔自治区电子信息材料与器件重点实验室新疆理化技术研究所_资源化学研究室
作者单位	Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China;Coll Chem & Chem Engn, Beijing 100039, Peoples R China
推荐引用方式 GB/T 7714	Yang Yun,Pan Shilie,Han Jian,et al. A New Lithium Rubidium Borate Li6Rb5B11O22 with Isolated B11O22 Building Blocks[J]. CRYSTAL GROWTH & DESIGN,2011,11(9):3912-3916.
APA	Yang Yun.,Pan Shilie.,Han Jian.,Hou Xueling.,Zhou Zhongxiang.,...&Zhang Min.(2011).A New Lithium Rubidium Borate Li6Rb5B11O22 with Isolated B11O22 Building Blocks.CRYSTAL GROWTH & DESIGN,11(9),3912-3916.
MLA	Yang Yun,et al."A New Lithium Rubidium Borate Li6Rb5B11O22 with Isolated B11O22 Building Blocks".CRYSTAL GROWTH & DESIGN 11.9(2011):3912-3916.