Self-assembly fibrillar network gels of simple surfactants in organic solvents
Wang D(王栋)
刊名Langmuir
2011
卷号27期号:5页码:1713-1717
ISSN号0743-7463
通讯作者郝京诚
中文摘要The self-assembled fibrillar network (SAFIN) organogels of a simple surfactant molecule, sodium laurate (C11H23COONa, SL), in organic solvents were investigated. The sol-gel transformation temperature depended on the SL concentration, the solvent, and the concentration ofNaþ was evaluated.An important finding is thatNaþ ions play an important role in forming organogels, which was regarded as the induction factor of gelation, but other cations, for instance, Li þ,Kþ, Ca2þ, and Mg2þ, do not have this capability. The observations by transmission electron microscopy (TEM) and scanning electron microscopy (SEM) proved that the organogels were network structures with fibers and ribbons by trapping a certain amount of organic solvent.High-resolution TEM(HR-TEM) images indicated that each of the fibers or ribbons was composed of cylindrical micelles. The X-ray diffraction (XRD) and Fourier transform infrared (FT-IR) spectra demonstrated that SL molecules in gels behave similarly to those in SL crystals. The mechanism of organogel formation was elaborated to provide a better understanding of fibrous surfactant gels in organic solvents.
学科主题材料科学与物理化学
收录类别SCI
资助信息the NSFC (grant NO.20625307 & 21033005);the National Basic Research Program of China (973 Program;2009CB930103);NFS of Shandong Province (Z2008B01)
语种英语
WOS记录号WOS:000287624700024
公开日期2012-09-24
内容类型期刊论文
源URL[http://210.77.64.217/handle/362003/780]  
专题兰州化学物理研究所_固体润滑国家重点实验室
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GB/T 7714
Wang D. Self-assembly fibrillar network gels of simple surfactants in organic solvents[J]. Langmuir,2011,27(5):1713-1717.
APA 王栋.(2011).Self-assembly fibrillar network gels of simple surfactants in organic solvents.Langmuir,27(5),1713-1717.
MLA 王栋."Self-assembly fibrillar network gels of simple surfactants in organic solvents".Langmuir 27.5(2011):1713-1717.
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