Spectral and thermal investigation of novel glycine-based schiff base derivative and its metal complexes

CORC > 兰州化学物理研究所 > 中国科学院兰州化学物理研究所 > 固体润滑国家重点实验室

	Spectral and thermal investigation of novel glycine-based schiff base derivative and its metal complexes
	Jiao TF(焦体峰) ; Zhou Y(周媛) ; Zhou JX(周靖欣) ; Xing YY(邢媛媛) ; Li YH(李阳辉)
刊名	Key Engineering Materials
	2011
卷号	474-476 页码:543-547
关键词	Glyscine Schiff base Metal complex Ligand Thermal stability
ISSN号	1662-9795
通讯作者	焦体峰
中文摘要	A novel glycine-based Schiff base derivative (abbreviated as C16GlySb) containing long alkyl chain was synthesized from glycine reacted with 4-cetyloxy-2-hydroxybenzaldehyde and sequentially coordinated with various metal ions to give the corresponding metal complexes (abbreviated as G-M). The products were characterized by UV-Vis spectra and FT-IR spectra. At the same time, the thermal stability was measured by TG-DTA instrument. FT-IR analysis indicated that the nitrogen atom in imino group, oxygen atom in phenolic hydroxyl group, and carboxylic ion participated in coordinating with transition metal ion in doubly-bridged mode. UV spectra showed that compared with ethanol solution, the cast film on quartz plate showed H-type or J-type aggregate structure. In addition, the thermal stability of G-M had been obviously superior to that of the ligand C16GlySb. The present results have showed potential application in fields of functional material and catalyst.
学科主题	材料科学与物理化学
收录类别	SCI
资助信息	the National Natural Science Foundation of China (NO.20903078);the Natural Science Foundation of Hebei Province (NO.B2009000347);Hundred Excellent Innovation Talents from Universities and Colleges of Hebei Province (NO.CPRC020);the Open Foundation of State Key Laboratory of Solid Lubrication (Lanzhou Institute of Chemical Physics;CAS) (NO.1002);the Scientific Research Plan of Education Department of Hebei Province (NO.Z2009146);the Scientific and Technological Research and Development Program of Qinhuangdao City (Nos. 201001A100;201001A101);the Doctoral Foundation of Yanshan University (NO.B360)
语种	英语
公开日期	2012-09-24
内容类型	期刊论文
源URL	[http://210.77.64.217/handle/362003/774]
专题	兰州化学物理研究所_固体润滑国家重点实验室
推荐引用方式 GB/T 7714	Jiao TF,Zhou Y,Zhou JX,et al. Spectral and thermal investigation of novel glycine-based schiff base derivative and its metal complexes[J]. Key Engineering Materials,2011,474-476:543-547.
APA	焦体峰,周媛,周靖欣,邢媛媛,&李阳辉.(2011).Spectral and thermal investigation of novel glycine-based schiff base derivative and its metal complexes.Key Engineering Materials,474-476,543-547.
MLA	焦体峰,et al."Spectral and thermal investigation of novel glycine-based schiff base derivative and its metal complexes".Key Engineering Materials 474-476(2011):543-547.