Creation of a monomeric Ag species on the surface of g-ZrP as an efficient heterogeneous catalyst for the selective oxidation of cycloolefins

CORC > 兰州化学物理研究所 > 中国科学院兰州化学物理研究所 > OSSO国家重点实验室

	Creation of a monomeric Ag species on the surface of g-ZrP as an efficient heterogeneous catalyst for the selective oxidation of cycloolefins
	Liu JH(刘俊华) ; Wang F(王丰) ; Xu XL(徐贤伦)
刊名	Catalysis Letters
	2008
卷号	120 页码:106-110
关键词	Allylic oxidation Cycloolefin Enols Silver Zirconium phosphates
ISSN号	1011-372X
通讯作者	徐贤伦
中文摘要	A hybrid complex Zr(PO4)(AgHPO4) was prepared by ion-exchange and its activity was examined on the allylic oxidation of cycloolefins using tert-butylhydroperoxide (TBHP) as oxidant under argon atmosphere. Under these reaction conditions, attack of the activated C–H bond was preferred instead of the epoxidation of C=C bond, yielding enols as the main products, this is a novel highly active/selective and reusable heterogeneous catalyst.
学科主题	物理化学
收录类别	SCI
语种	英语
公开日期	2012-11-09
内容类型	期刊论文
源URL	[http://210.77.64.217/handle/362003/1987]
专题	兰州化学物理研究所_OSSO国家重点实验室
推荐引用方式 GB/T 7714	Liu JH,Wang F,Xu XL. Creation of a monomeric Ag species on the surface of g-ZrP as an efficient heterogeneous catalyst for the selective oxidation of cycloolefins[J]. Catalysis Letters,2008,120:106-110.
APA	刘俊华,王丰,&徐贤伦.(2008).Creation of a monomeric Ag species on the surface of g-ZrP as an efficient heterogeneous catalyst for the selective oxidation of cycloolefins.Catalysis Letters,120,106-110.
MLA	刘俊华,et al."Creation of a monomeric Ag species on the surface of g-ZrP as an efficient heterogeneous catalyst for the selective oxidation of cycloolefins".Catalysis Letters 120(2008):106-110.