Simultaneous determination of tin, nickel, lead, cadmium and mercury in cigarette material by solid phase extraction and HPLC

CORC > 昆明植物研究所 > 中国科学院昆明植物研究所 > 植物化学与西部植物资源持续利用国家重点实验室

	Simultaneous determination of tin, nickel, lead, cadmium and mercury in cigarette material by solid phase extraction and HPLC
	Hu, Q; Yang, GY ; Ma, J ; Liu, JK
刊名	BULLETIN OF THE KOREAN CHEMICAL SOCIETY
	2003-10-20
卷号	24 期号:10 页码:1433-1436
关键词	RP-HPLC tetra-(2-chlorophenyl)-porphyrin solid phase extraction heavy metal
ISSN号	0253-2964
通讯作者	Hu, Q (reprint author), Chinese Acad Sci, Inst Kunming Bot, Kunming 650223, Peoples R China.
英文摘要	A new method for the simultaneous determination of heavy metal ions in cigarette material by microwave digestion and reversed-phase high-performance liquid chromatography (RP-HPLC) has been developed. The cigarette material was digested by microwave digestion. Lead, cadmium, mercury, nickel and tin ions in the digested samples were pre-column derivatized with tetra-(2-chlorophenyl)-porphyrin (T-2-CPP) to form color chelates, which were then enriched by solid phase extraction with a C-18 cartridge. The chelates were separated on a Waters Xterra(TM) RP18 column by gradient elution with methanol (containing 0.05 mol/L pyrrolidine-acetic acid buffer salt, pH = 10.0) and acetone (containing 0.05 mol/L pyrrolidine-acetic acid buffer salt, pH = 10.0) as mobile phase at a flow rate of 0.5 mL/min and analyzed with a photodiode array detector from 350-600 nm. The detection limits of lead, cadmium, mercury, nickel and tin were 4, 3, 3, 8, and 5 ng/L, respectively, in the original samples. This method was afforded good results.
学科主题	Chemistry, Multidisciplinary
类目[WOS]	Chemistry, Multidisciplinary
研究领域[WOS]	Chemistry
关键词[WOS]	PERFORMANCE LIQUID-CHROMATOGRAPHY ; COMPLEXES ; METAL ; COPPER(II)
收录类别	SCI
语种	英语
WOS记录号	WOS:000186413100004
公开日期	2012-10-12
内容类型	期刊论文
源URL	[http://ir.kib.ac.cn/handle/151853/15460]
专题	昆明植物研究所_植物化学与西部植物资源持续利用国家重点实验室
作者单位	1.Chinese Acad Sci, Inst Kunming Bot, Kunming 650223, Peoples R China 2.Yunnan Acad Tobacco Sci, Inst Ind, Kunming 650106, Peoples R China
推荐引用方式 GB/T 7714	Hu, Q,Yang, GY,Ma, J,et al. Simultaneous determination of tin, nickel, lead, cadmium and mercury in cigarette material by solid phase extraction and HPLC[J]. BULLETIN OF THE KOREAN CHEMICAL SOCIETY,2003,24(10):1433-1436.
APA	Hu, Q,Yang, GY,Ma, J,&Liu, JK.(2003).Simultaneous determination of tin, nickel, lead, cadmium and mercury in cigarette material by solid phase extraction and HPLC.BULLETIN OF THE KOREAN CHEMICAL SOCIETY,24(10),1433-1436.
MLA	Hu, Q,et al."Simultaneous determination of tin, nickel, lead, cadmium and mercury in cigarette material by solid phase extraction and HPLC".BULLETIN OF THE KOREAN CHEMICAL SOCIETY 24.10(2003):1433-1436.