2-Ethyl-ketimino-1,10-phenanthroline iron(II) complexes as highly active catalysts for ethylene oligomerization

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	2-Ethyl-ketimino-1,10-phenanthroline iron(II) complexes as highly active catalysts for ethylene oligomerization
	Zhang M(张民) ; Zhang WJ(张文娟) ; 肖田鹏飞 ; Xiang JF(向俊峰) ; Hao X(郝项) ; Sun WH(孙文华)
刊名	J. Mol. Catal. A: Chem.
	2010
卷号	320 页码:92-96
关键词	2-Ethyl-ketimino-1 Iron(II) complexes Ethylene oligomerization 10-phenanthroline
ISSN号	1381-1169
通讯作者	孙文华
中文摘要	A series of 2-(1-aryliminopropyl)-1,10-phenanthrolines (L1–L7) and their corresponding iron(II) chlorides (Fe1–Fe7) are synthesized and characterized by elemental and spectroscopic analyses. The molecular structures of 2-[1-(2,6-diisopropy1phenylimino)propyl]-1,10-phenanthroline (L3) and {2-[1-(2,6-diethylphenylimino)propyl]-1,10-phenanthroline}·FeCl2 (Fe2) are determined by the single crystal X-ray diffraction. All iron complexes, activated with methylaluminoxane (MAO), exhibit high activities in ethylene oligomerization with high selectivity for -olefins produced. Compared with other 2-iminophenanthrolines, the title complexes show better thermal stability, and their oligomerization products are potentially more useful due to lower contents of butenes and waxes observed.
学科主题	物理化学
收录类别	SCI
资助信息	NSFC no. 20674089
语种	英语
WOS记录号	WOS:000276011600014
公开日期	2012-09-21
内容类型	期刊论文
源URL	[http://210.77.64.217/handle/362003/476]
专题	兰州化学物理研究所_OSSO国家重点实验室
推荐引用方式 GB/T 7714	Zhang M,Zhang WJ,肖田鹏飞,et al. 2-Ethyl-ketimino-1,10-phenanthroline iron(II) complexes as highly active catalysts for ethylene oligomerization[J]. J. Mol. Catal. A: Chem.,2010,320:92-96.
APA	张民,张文娟,肖田鹏飞,向俊峰,郝项,&孙文华.(2010).2-Ethyl-ketimino-1,10-phenanthroline iron(II) complexes as highly active catalysts for ethylene oligomerization.J. Mol. Catal. A: Chem.,320,92-96.
MLA	张民,et al."2-Ethyl-ketimino-1,10-phenanthroline iron(II) complexes as highly active catalysts for ethylene oligomerization".J. Mol. Catal. A: Chem. 320(2010):92-96.