Anion Binding of a Protonated Tripodal Tris(ferrocenylurea) Receptor

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	Anion Binding of a Protonated Tripodal Tris(ferrocenylurea) Receptor
	Yang XJ(杨晓娟); Huang XJ(黄晓卷)
刊名	Z. Anorg. Allg. Chem.
	2011
卷号	637 页码:2306-2311
关键词	Tripodal tris-urea receptors Ferrocene Anion binding Protonation NMR spectroscopy
ISSN号	0044-2313
通讯作者	吴彪
中文摘要	Two anion complexes of a tripodal tris(ferrocenylurea) receptor (L), (LH)·CF3SO3 (1) and (LH)·HSO4 (2), were obtained from L and triflic acid or sulfuric acid, respectively. Crystal structural analyses show that the receptor in the two 1:1 (host/guest) complexes isprotonated (on the bridgehead tertiary amine), and the CF3SO3 – or HSO4 – anion is located outside the tripodal cavity and anchored by the urea and CH groups of the receptor by hydrogen bonds. 1H NMR spectroscopic studies confirmed the binding mode in solution.
学科主题	金属有机
收录类别	SCI
资助信息	the National Natural Science Foundation of China (20872149)
语种	英语
WOS记录号	WOS:000298478600039
公开日期	2012-09-20
内容类型	期刊论文
源URL	[http://210.77.64.217/handle/362003/322]
专题	兰州化学物理研究所_OSSO国家重点实验室兰州化学物理研究所_ERC国家工程研究中心
推荐引用方式 GB/T 7714	Yang XJ,Huang XJ. Anion Binding of a Protonated Tripodal Tris(ferrocenylurea) Receptor[J]. Z. Anorg. Allg. Chem.,2011,637:2306-2311.
APA	杨晓娟,&黄晓卷.(2011).Anion Binding of a Protonated Tripodal Tris(ferrocenylurea) Receptor.Z. Anorg. Allg. Chem.,637,2306-2311.
MLA	杨晓娟,et al."Anion Binding of a Protonated Tripodal Tris(ferrocenylurea) Receptor".Z. Anorg. Allg. Chem. 637(2011):2306-2311.