Synthesis of rosin-based imidoamine-type curing agents and curing behavior with epoxy resin

	Synthesis of rosin-based imidoamine-type curing agents and curing behavior with epoxy resin
	Wang HH ; Wang HW ; Zhou GY
刊名	polymer international
	2011
卷号	60 期号:4 页码:557-563
关键词	MALEOPIMARIC ACID ANHYDRIDE POLY(BUTYLENE SUCCINATE) LEVOPIMARIC ACID MALEIC-ANHYDRIDE ACRYLIC-ACID KINETICS DERIVATIVES POLYMERS POLYMERIZATION ADDUCT
ISSN号	0959-8103
通讯作者	wang hh
中文摘要	rosin is an abundantly available natural product. the characteristic fused ring structure of rosin acids is analogous to that of some aromatic compounds in rigidity, and makes rosin and its derivatives potential substitutes for those aromatic compounds. in the study reported, the synthesis of biobased curing agents containing imide structure using rosin and the cure reaction were investigated. rosin-based imidoamine-type curing agents were synthesized, and the chemical structure was confirmed using (1)h nmr, fourier transform infrared and electrospray ionization spectroscopy. the curing behavior with diglycidyl ether of bisphenol a epoxy was studied using differential scanning calorimetry. the thermal mechanical properties and thermal stability of the cured epoxy resins were evaluated using dynamic mechanical analysis and thermogravimetry, respectively. the results indicate that the curing behavior of the rosin-based curing agents is similar to that of curing agents with analogous structures. cured products have good thermal stability due to the presence of the imide group and the bulky hydrogenated phenanthrene ring structure. rosin acids have a great potential in the synthesis of epoxy curing agents as replacements for some of the current commercial aromatic or cycloaliphatic analogues. (c) 2010 society of chemical industry
收录类别	SCI收录期刊论文
语种	英语
WOS记录号	WOS:000288618500005
公开日期	2012-06-11
内容类型	期刊论文
源URL	[http://ir.ciac.jl.cn/handle/322003/44734]
专题	长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式 GB/T 7714	Wang HH,Wang HW,Zhou GY. Synthesis of rosin-based imidoamine-type curing agents and curing behavior with epoxy resin[J]. polymer international,2011,60(4):557-563.
APA	Wang HH,Wang HW,&Zhou GY.(2011).Synthesis of rosin-based imidoamine-type curing agents and curing behavior with epoxy resin.polymer international,60(4),557-563.
MLA	Wang HH,et al."Synthesis of rosin-based imidoamine-type curing agents and curing behavior with epoxy resin".polymer international 60.4(2011):557-563.