Ferrous and cobaltous chloride complexes bearing 2-(1-(arylimino)methyl)-8-(1H-benzimidazol-2-yl)quinolines: Synthesis, characterization and catalytic behavior in ethylene polymerization

	Ferrous and cobaltous chloride complexes bearing 2-(1-(arylimino)methyl)-8-(1H-benzimidazol-2-yl)quinolines: Synthesis, characterization and catalytic behavior in ethylene polymerization
	Xiao TPF ; Zhang S ; Li BX ; Hao X ; Redshaw C ; Li YS ; Sun WH
刊名	polymer
	2011
卷号	52 期号:25 页码:5803-5810
关键词	TRIDENTATE BIS(IMINO)PYRIDINE COMPLEXES 2 HIGH-TEMPERATURE CATALYSTS 6-BIS(IMINO)PYRIDYL IRON HIGHLY-ACTIVE CATALYSTS OLEFIN POLYMERIZATION ALPHA-OLEFINS STRUCTURAL-CHARACTERIZATION ELECTRONIC-STRUCTURES DIIMINE COMPLEXES METAL FE
ISSN号	0032-3861
通讯作者	sun wh
中文摘要	the series of ligands 2-(1-(arylimino)methyl)-8-(1h-benzimidazol-2-yl)quinolines was synthesized and used to prepare new iron(ii) and cobalt(ii) dichloride complexes. x-ray diffraction studies revealed that the coordination geometry around the metal center can best be described as distorted square-based pyramidal. upon activation with methylaluminoxane (mao), both families (fe and co) of complexes showed good activities in ethylene polymerization, affording highly linear polyethylenes. enhanced activities were observed on increasing the reaction temperature to 100 degrees c. the optimization of the reaction parameters and the influence of the substituents on the imino-bound aryl group of the chelate ligands were investigated. (c) 2011 elsevier ltd. all rights reserved.
收录类别	SCI收录期刊论文
语种	英语
WOS记录号	WOS:000297539000015
公开日期	2012-06-08
内容类型	期刊论文
源URL	[http://ir.ciac.jl.cn/handle/322003/44212]
专题	长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式 GB/T 7714	Xiao TPF,Zhang S,Li BX,et al. Ferrous and cobaltous chloride complexes bearing 2-(1-(arylimino)methyl)-8-(1H-benzimidazol-2-yl)quinolines: Synthesis, characterization and catalytic behavior in ethylene polymerization[J]. polymer,2011,52(25):5803-5810.
APA	Xiao TPF.,Zhang S.,Li BX.,Hao X.,Redshaw C.,...&Sun WH.(2011).Ferrous and cobaltous chloride complexes bearing 2-(1-(arylimino)methyl)-8-(1H-benzimidazol-2-yl)quinolines: Synthesis, characterization and catalytic behavior in ethylene polymerization.polymer,52(25),5803-5810.
MLA	Xiao TPF,et al."Ferrous and cobaltous chloride complexes bearing 2-(1-(arylimino)methyl)-8-(1H-benzimidazol-2-yl)quinolines: Synthesis, characterization and catalytic behavior in ethylene polymerization".polymer 52.25(2011):5803-5810.