Constraining the colouration mechanisms of Cretaceous Oceanic Red Beds;using diffuse reflectance spectroscopy | |
Li, Xiang1; Cai, Yuanfeng1,2 | |
刊名 | CRETACEOUS RESEARCH |
2013 | |
卷号 | 46页码:257-266 |
关键词 | Cretaceous Oceanic Red Beds Hematite Diffuse reflectance spectroscopy Colouration mechanisms |
ISSN号 | 0195-6671;EI 1095-998X |
DOI | 10.1016/j.cretres.2013.09.009 |
英文摘要 | We have used diffuse reflectance spectroscopy to investigate the colouration mechanisms of hematite in Cretaceous Oceanic Red Beds (CORBs). Data for samples of CORBs from the Chuangde section in Tibet, Vispi Quarry section in Italy, and Core 12X of Ocean Drilling Program Hole 1049C in the North Atlantic were compared with calibration datasets obtained for hematite in different crystalline forms (kidney and specular hematite) and calcite matrix. Spectra for hematite in either pure form or in calibration datasets show that the centre of the reflection peak shifts to a longer wavelength and depth (D) decreases as the crystallinity of the hematite increases. Compared with specular hematite, the presence of just 0.5% of kidney hematite can cause a much deeper absorption peak and greater redness value, which indicates that kidney hematite has a higher colouration capacity than specular hematite. However, both kidney and specular hematite exhibit a good correlation between the redness value for each calibration dataset and the absorption peak depth. In all three studied sections, hematite is the main iron oxide mineral responsible for colouration. Spectral features such as absorption peak depth and peak centre reveal that hematite crystallinity gradually decreases from red shale to limestone to marl. Based on a spectral comparison of red shale in the Chuangde section before and after citrate-bicarbonate-dithionite (CBD) treatment, we found that two forms of hematite are present: a fine-grained and dispersed form, and a detrital form. The former is relatively poorly crystalline hematite, which has a much stronger colouration capacity than the detrital form. In the Vispi Quarry section and Core 12X of ODP Hole 1049C, a good correlation between the absorption peak depth of hematite and redness value indicates that the red colouration is caused by hematite of similar crystallinity in each section. (C) 2013 Elsevier Ltd. All rights reserved. |
学科主题 | 地层学与地史学 |
WOS关键词 | NORTH-ATLANTIC DRIFTS ; VISPI QUARRY SECTION ; PALEOCEANOGRAPHIC ; SIGNIFICANCE ; MINERALOGICAL CHARACTERISTICS ; VISIBLE SPECTROSCOPY ; MARINE-SEDIMENTS ; SOUTHERN TIBET ; OXIDE MINERALS ; IRON-OXIDES ; SOIL ; COLOR |
WOS研究方向 | Geology ; Paleontology |
语种 | 英语 |
出版者 | ACADEMIC PRESS LTD- ELSEVIER SCIENCE LTD |
WOS记录号 | WOS:000329553900020 |
内容类型 | 期刊论文 |
源URL | [http://119.78.100.197/handle/2HKVOGP0/39917] |
专题 | 中国地质调查局 |
作者单位 | 1.China Geol Survey, Wuhan Inst Geol & Mineral Resources, Wuhan 430223, Peoples R China. 2.Nanjing Univ, Sch Earth Sci & Engn, Nanjing 210046, Jiangsu, Peoples R China. 3.Nanjing Univ, State Key Lab Mineral Deposits Res, Nanjing 210046, Jiangsu, Peoples R China. |
推荐引用方式 GB/T 7714 | Li, Xiang,Cai, Yuanfeng. Constraining the colouration mechanisms of Cretaceous Oceanic Red Beds;using diffuse reflectance spectroscopy[J]. CRETACEOUS RESEARCH,2013,46:257-266. |
APA | Li, Xiang,&Cai, Yuanfeng.(2013).Constraining the colouration mechanisms of Cretaceous Oceanic Red Beds;using diffuse reflectance spectroscopy.CRETACEOUS RESEARCH,46,257-266. |
MLA | Li, Xiang,et al."Constraining the colouration mechanisms of Cretaceous Oceanic Red Beds;using diffuse reflectance spectroscopy".CRETACEOUS RESEARCH 46(2013):257-266. |
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