Determination of Hydration Number of Methane Hydrates Using Micro-Laser Raman Spectroscopy

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	Determination of Hydration Number of Methane Hydrates Using Micro-Laser Raman Spectroscopy
	Liu, CL (Liu Chang-ling)5; Ye, YG (Ye Yu-guang); Meng, QG (Meng Qing-guo)
刊名	SPECTROSCOPY AND SPECTRAL ANALYSIS
	2010
卷号	30 期号:4 页码:963-966
关键词	Methane hydrates Laser Raman spectroscopy Hydration number Cage occupancy
ISSN号	1000-0593
英文摘要	Methane hydrates are clathrate compounds that are formed by methane molecules and water molecules under low temperature and high pressure conditions. It was found that methane hydrates exist widely in sea-shelf floor and permafrost, and are considered as a potential energy resource. In the crystal lattice of clathrate hydrate, the water molecules form both large cages (5(12)6(2)) and small cages (5(12)) under the interaction of the hydrogen-hydrogen bond. In this paper, the authors designed a set of experimental apparatus for methane hydrates formation. Based on this equipment, the authors synthesized a series of methane hydrates in various systems in laboratory, including SDS solution (3% Wt) and methane, powdered ice and methane, and powdered ice and methane and natural sand with various sizes (i. e. 250-350, 180-250, 125-180 and 63-90 mu m), under different temperature and pressure. The authors also designed a small device which was proved to be convenient for Raman determination of the methane hydrates. Raman spectroscopy was used to analyze the methane hydrates and to measure the structural parameters such as hydration numbers and cage occupancies. The results show that the methane hydrate samples are all in structure I type, and hydration numbers and cage occupancies are almost independent of the sediment sizes. In the three systems, the large cages of methane hydrate samples are nearly full occupied, with the occupancy ratios larger than 97%, whereas the small cages between 80% and 86%. The hydration numbers of these methane hydrate samples are between 6. 05 and 6. 15.
学科主题	岩矿鉴定与测试
WOS关键词	INTERNAL STANDARD METHOD ; GAS HYDRATE ; FLUID INCLUSIONS ; CAGE OCCUPANCY ; MIXED-GAS ; DEPOSIT
WOS研究方向	Spectroscopy
语种	中文
出版者	OFFICE SPECTROSCOPY & SPECTRAL ANALYSIS
WOS记录号	WOS:000276506100022
内容类型	期刊论文
源URL	[http://119.78.100.197/handle/2HKVOGP0/39096]
专题	中国地质调查局
作者单位	1.[Liu Chang-ling 2.Ye Yu-guang 3.Minist Land & Resources, Key Lab Marine Hydrocarbon Resources & Environm G, Qingdao 266071, Peoples R China [Liu Chang-ling 4.Qingdao Univ, Coll Chem & Chem Engn, Qingdao 266071, Peoples R China 5.中国地质调查局青岛海洋地质研究所
推荐引用方式 GB/T 7714	Liu, CL ,Ye, YG ,Meng, QG . Determination of Hydration Number of Methane Hydrates Using Micro-Laser Raman Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS,2010,30(4):963-966.
APA	Liu, CL ,Ye, YG ,&Meng, QG .(2010).Determination of Hydration Number of Methane Hydrates Using Micro-Laser Raman Spectroscopy.SPECTROSCOPY AND SPECTRAL ANALYSIS,30(4),963-966.
MLA	Liu, CL ,et al."Determination of Hydration Number of Methane Hydrates Using Micro-Laser Raman Spectroscopy".SPECTROSCOPY AND SPECTRAL ANALYSIS 30.4(2010):963-966.