Fluorine and nitrogen co-doped ordered mesoporous carbon as a metal-free   electrocatalyst for oxygen reduction reaction

doi:10.1039/c6ra14748h

CORC > 北京大学 > 工学院

	Fluorine and nitrogen co-doped ordered mesoporous carbon as a metal-free electrocatalyst for oxygen reduction reaction
	Wang, Haiwen ; Ding, Junjie ; Zhang, Jiao ; Wang, Chenfei ; Yang, Wenlong ; Ren, Hongxin ; Kong, Aiguo
刊名	RSC ADVANCES
	2016
关键词	AMORPHOUS-CARBON FUEL-CELLS CATALYSTS PERFORMANCE FRAMEWORKS NANOSHEETS PLATINUM CATHODE BLACKS SULFUR
DOI	10.1039/c6ra14748h
英文摘要	Fluorine and nitrogen co-doped ordered mesoporous carbon (FN-OMC) is synthesized by a hard template method employing inexpensive resorcin as a carbon precursor and ammonium fluoride as a fluorine and nitrogen source. Considerable fluorine and nitrogen atoms (F: 0.35 at%, N: 2.25 at%) are homogeneously implanted in the graphitic carbon matrix with high surface area (671.3 cm(2) g(-1)) and ordered mesoporous channels (6.2 nm). The FN-OMC prepared at the optimized heat-treatment temperature (1000 degrees C) exhibits a high catalytic activity (E-onset: -0.07 V, E-1/2: -0.19 V, current density: 5.83 mA cm(-2)) for oxygen reduction reaction (ORR) comparable to commercial platinum-carbon (Pt-C, 20 wt%) catalysts, but better stability and methanol-tolerance in alkaline solutions. The synergistic effect of fluorine and nitrogen atoms in carbon frameworks is demonstrated to sharply polarize adjacent carbon atoms and facilitate the formation of defect-induced active sites for ORR.; Shanghai construction of college experiment technique team plan [YJ0114204]; SCI(E); EI; ARTICLE; wanghaiwen0707@163.com; 83; 79928-79933; 6
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/492446]
专题	工学院
推荐引用方式 GB/T 7714	Wang, Haiwen,Ding, Junjie,Zhang, Jiao,et al. Fluorine and nitrogen co-doped ordered mesoporous carbon as a metal-free electrocatalyst for oxygen reduction reaction[J]. RSC ADVANCES,2016.
APA	Wang, Haiwen.,Ding, Junjie.,Zhang, Jiao.,Wang, Chenfei.,Yang, Wenlong.,...&Kong, Aiguo.(2016).Fluorine and nitrogen co-doped ordered mesoporous carbon as a metal-free electrocatalyst for oxygen reduction reaction.RSC ADVANCES.
MLA	Wang, Haiwen,et al."Fluorine and nitrogen co-doped ordered mesoporous carbon as a metal-free electrocatalyst for oxygen reduction reaction".RSC ADVANCES (2016).