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Estimating Soil Organic Carbon of Cropland Soil at Different Levels of Soil Moisture Using VIS-NIR Spectroscopy
Jiang, Qinghu ; Chen, Yiyun ; Guo, Long ; Fei, Teng ; Qi, Kun
刊名REMOTE SENSING
2016
关键词generalized least squares weighting moisture correction orthogonal signal correction soil organic carbon visible near-infrared reflectance spectroscopy NEAR-INFRARED-SPECTROSCOPY DIFFUSE-REFLECTANCE SPECTROSCOPY AGRICULTURAL SOILS FIELD CONDITIONS CENTRAL YANGTZE LEAST-SQUARES WATER CONTENT SPECTRA PREDICTION QUANTIFICATION
DOI10.3390/rs8090755
英文摘要Soil organic carbon (SOC) is an essential property for soil function, fertility and sustainability of agricultural systems. It can be measured with visible and near-infrared reflectance (VIS-NIR) spectroscopy efficiently based on empirical equations and spectra data for air/oven-dried samples. However, the spectral signal is interfered with by soil moisture content (MC) under in situ conditions, which will affect the accuracy of measurements and calibration transfer among different areas. This study aimed to (1) quantify the influences of MC on SOC prediction by VIS-NIR spectroscopy; and (2) explore the potentials of orthogonal signal correction (OSC) and generalized least squares weighting (GLSW) methods in the removal of moisture interference. Ninety-eight samples were collected from the Jianghan plain, China, and eight MCs were obtained for each sample by a rewetting process. The VIS-NIR spectra of the rewetted soil samples were measured in the laboratory. Partial least squares regression (PLSR) was used to develop SOC prediction models. Specifically, three validation strategies, namely moisture level validation, transferability validation and mixed-moisture validation, were designed to test the potentials of OSC and GLSW in removing the MC effect. Results showed that all of the PLSR models generated at different moisture levels (e.g., 50-100, 250-300 gkg(-1)) were moderately successful in SOC predictions (r(pre)(2) = 0.58-0.85, RPD = 1.55-2.55). These models, however, could not be transferred to soil samples with different moisture levels. OSC and GLSW methods are useful filter transformations improving model transferability. The GLSW-PLSR model (mean of r(pre)(2) = 0.77, root mean square error for prediction (RMSEP) = 3.08 gkg(-1), and residual prediction deviations (RPD) = 2.09) outperforms the OSC-PLSR model (mean of r(pre)(2) = 0.67, RMSEP = 3.67 gkg(-1), and RPD = 1.76) when the moisture-mixed protocol is used. Results demonstrated the use of OSC and GLSW combined with PLSR models for efficient estimation of SOC using VIS-NIR under different soil MC conditions.; National Natural Science Foundation of China [31600377, 41501444]; Fundamental Research Funds for the Central Universities [2042015KF1044]; Suzhou Applied and Basic Research Program for Agriculture [SYN201422]; SCI(E); ARTICLE; jianghu_568@163.com; chenyy@whu.edu.cn; guolong027@tom.com; feiteng@whu.edu.cn; qikun@whu.edu.cn; 9; 8
语种英语
内容类型期刊论文
源URL[http://ir.pku.edu.cn/handle/20.500.11897/458910]  
专题工学院
推荐引用方式
GB/T 7714
Jiang, Qinghu,Chen, Yiyun,Guo, Long,et al. Estimating Soil Organic Carbon of Cropland Soil at Different Levels of Soil Moisture Using VIS-NIR Spectroscopy[J]. REMOTE SENSING,2016.
APA Jiang, Qinghu,Chen, Yiyun,Guo, Long,Fei, Teng,&Qi, Kun.(2016).Estimating Soil Organic Carbon of Cropland Soil at Different Levels of Soil Moisture Using VIS-NIR Spectroscopy.REMOTE SENSING.
MLA Jiang, Qinghu,et al."Estimating Soil Organic Carbon of Cropland Soil at Different Levels of Soil Moisture Using VIS-NIR Spectroscopy".REMOTE SENSING (2016).
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