Elastomeric Conducting Polyaniline Formed Through Topological Control of   Molecular Templates

doi:10.1021/acsnano.6b01520

CORC > 北京大学 > 工学院

	Elastomeric Conducting Polyaniline Formed Through Topological Control of Molecular Templates
	Ding, Hangjun ; Zhong, Mingjiang ; Wu, Haosheng ; Park, Sangwoo ; Mohin, Jacob W. ; Klosterman, Luke ; Yang, Zhou ; Yang, Huai ; Matyjaszewski, Krzysztof ; Bettinger, Christopher John
刊名	ACS NANO
	2016
关键词	conducting polymer flexible electronics nanostructure block copolymer TRANSFER RADICAL POLYMERIZATION BLOCK-COPOLYMERS STRETCHABLE ELECTRONICS EMULSION POLYMERIZATION CONJUGATED POLYMERS DIBLOCK COPOLYMERS FILM COMPOSITES SUPERCAPACITOR PERCOLATION STYRENE
DOI	10.1021/acsnano.6b01520
英文摘要	A strategy for creating elastomeric conducting polyaniline networks is described. Simultaneous elastomeric mechanical properties (E < 10 MPa) and electronic conductivities (sigma > 10 S cm(-1)) are achieved via molecular templating of conjugated polymer networks. Diblock copolymers with star topologies processed into self-assembled elastomeric thin films reduce the percolation threshold of polyaniline synthesized via in situ polymerization. Block copolymer templates with star topologies produce elastomeric conjugated polymer composites with Young's moduli ranging from 4 to 12 MPa, maximum elongations up to 90 +/- 10%, and electrical conductivities of 30 +/- 10 S cm(-1). Templated polyaniline films exhibit Young's moduli up to 3 orders of magnitude smaller compared to bulk polyaniline films while preserving comparable bulk electronic conductivity. Flexible conducting polymers have prospective applications in devices for energy storage and conversion, consumer electronics, and bioelectronics.; Carnegie Mellon Lian Ji Dan Fellowship; Defense Advanced Research Projects Agency [D14AP00040]; National Science Foundation [DMR 1501324]; National Institutes of Health [R21EB015165]; Natural Science Foundation of China [NSFC51273022, NSFC51373024]; Molecular Biosensor & Imaging Center in Carnegie Mellon University; Bruce and Astrid McWilliams Fellowship; SCI(E); EI; PubMed; ARTICLE; huaiyang@pek.edu.cn; km3b@andrew.cmu.edu; cbetting@andrew.cmu.edu; 6; 5991-5998; 10
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/433756]
专题	工学院
推荐引用方式 GB/T 7714	Ding, Hangjun,Zhong, Mingjiang,Wu, Haosheng,et al. Elastomeric Conducting Polyaniline Formed Through Topological Control of Molecular Templates[J]. ACS NANO,2016.
APA	Ding, Hangjun.,Zhong, Mingjiang.,Wu, Haosheng.,Park, Sangwoo.,Mohin, Jacob W..,...&Bettinger, Christopher John.(2016).Elastomeric Conducting Polyaniline Formed Through Topological Control of Molecular Templates.ACS NANO.
MLA	Ding, Hangjun,et al."Elastomeric Conducting Polyaniline Formed Through Topological Control of Molecular Templates".ACS NANO (2016).