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Integration of coal gasification and waste heat recovery from high temperature steel slags: an emerging strategy to emission reduction
Sun, Yongqi ; Sridhar, Seetharaman ; Liu, Lili ; Wang, Xidong ; Zhang, Zuotai
刊名Scientific Reports
2015
关键词DIRECT REDUCED IRON BLAST-FURNACE SLAG BIOMASS GASIFICATION HYDROGEN-PRODUCTION ENERGY EFFICIENCY STEELMAKING SLAG THERMAL-ANALYSIS WATER-VAPOR MOLTEN SLAG HOT SLAG
DOI10.1038/srep16591
英文摘要With the continuous urbanization and industrialization in the world, energy saving and greenhouse gas (GHG) emission reduction have been serious issues to be addressed, for which heat recovery from traditional energy-intensive industries makes up a significant strategy. Here we report a novel approach to extract the waste heat and iron from high temperature steel slags (1450-1650 degrees C) produced in the steel industry, i.e., integration of coal gasification and steel slag treatment. Both the thermodynamics and kinetics of the pertinent reactions were identified. It was clarified that the kinetic mechanism for gasification varied from A2 model to A4 model (Avrami-Erofeev) in the presence of slags. Most importantly, the steel slags acted not only as good heat carriers but also as effective catalysts where the apparent activation energy for char gasification got remarkably reduced from 95.7 kJ/mol to 12.1 kJ/mol (A2 model). Furthermore, the FeO in the slags was found to be oxidized into Fe3O4, with an extra energy release, which offered a potential for magnetic separation. Moreover, based on the present research results, an emerging concept, composed of multiple industrial sectors, was proposed, which could serve as an important route to deal with the severe environmental problems in modern society.; National High Technology Research and Development Program of China (863 Program) [2012AA06A114]; Key Projects in the National Science & Technology Pillar Program [2013BAC14B07]; Common Development Fund of Beijing; National Natural Science Foundation of China [51472007, 51272005, 51172001]; SCI(E); PubMed; ARTICLE; zuotaizhang@pku.edu.cn; 16591; 5
语种英语
内容类型期刊论文
源URL[http://ir.pku.edu.cn/handle/20.500.11897/416871]  
专题工学院
推荐引用方式
GB/T 7714
Sun, Yongqi,Sridhar, Seetharaman,Liu, Lili,et al. Integration of coal gasification and waste heat recovery from high temperature steel slags: an emerging strategy to emission reduction[J]. Scientific Reports,2015.
APA Sun, Yongqi,Sridhar, Seetharaman,Liu, Lili,Wang, Xidong,&Zhang, Zuotai.(2015).Integration of coal gasification and waste heat recovery from high temperature steel slags: an emerging strategy to emission reduction.Scientific Reports.
MLA Sun, Yongqi,et al."Integration of coal gasification and waste heat recovery from high temperature steel slags: an emerging strategy to emission reduction".Scientific Reports (2015).
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