Effects of U-ore on the chemical and isotopic composition of products of   hydrous pyrolysis of organic matter

doi:10.1007/s12182-017-0161-6

CORC > 北京大学 > 地球与空间科学学院

	Effects of U-ore on the chemical and isotopic composition of products of hydrous pyrolysis of organic matter
	Cai, Yu-Wen ; Zhang, Shui-Chang ; He, Kun ; Mi, Jing-Kui ; Zhang, Wen-Long ; Wang, Xiao-Mei ; Wang, Hua-Jian ; Wu, Chao-Dong
刊名	PETROLEUM SCIENCE
	2017
关键词	Organic-inorganic interaction Hydrous pyrolysis Stable isotopes U-ore Carbocation mechanism TRANSITION-METAL CATALYSIS NATURAL-GAS LABORATORY EXPERIMENTS THERMAL ALTERATION HYDROCARBON GASES KEROGEN PYROLYSIS SOURCE ROCKS N-ALKANES GENERATION WATER
DOI	10.1007/s12182-017-0161-6
英文摘要	In order to investigate the impact of U-ore on organic matter maturation and isotopic fractionation, we designed hydrous pyrolysis experiments on Type-II kerogen samples, supposing that the water and water-mineral interaction play a role. U-ore was set as the variable for comparison. Meanwhile, anhydrous pyrolysis under the same conditions was carried out as the control experiments. The determination of liquid products indicates that the presence of water and minerals obviously enhanced the yields of C15+ and the amounts of hydrocarbon and non-hydrocarbon gases. Such results may be attributed to water-organic matter reaction in the high-temperature system, which can provide additional hydrogen and oxygen for the generation of gas and liquid products from organic matter. It is found that delta D values of hydrocarbon gases generated in both hydrous pyrolysis experiments are much lower than those in anhydrous pyrolysis. What is more, dD values are lower in the hydrous pyrolysis with uranium ore. Therefore, we can infer that water-derived hydrogen played a significant role during the kerogen thermal evolution and the hydrocarbon generation in our experiments. Isotopic exchange was facilitated by the reversible equilibration between reaction intermediaries with hydrogen under hydrothermal conditions with uranium ore. Carbon isotopic fractionations of hydrocarbon gases were somehow affected by the presence of water and the uranium ore. The increased level of i-C-4/n-C-4 ratios for gas products in hydrous pyrolysis implied the carbocation mechanism for water-kerogen reactions.; SCI(E); 中国科学引文数据库(CSCD); ARTICLE; 2; 315-329; 14
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/473646]
专题	地球与空间科学学院
推荐引用方式 GB/T 7714	Cai, Yu-Wen,Zhang, Shui-Chang,He, Kun,et al. Effects of U-ore on the chemical and isotopic composition of products of hydrous pyrolysis of organic matter[J]. PETROLEUM SCIENCE,2017.
APA	Cai, Yu-Wen.,Zhang, Shui-Chang.,He, Kun.,Mi, Jing-Kui.,Zhang, Wen-Long.,...&Wu, Chao-Dong.(2017).Effects of U-ore on the chemical and isotopic composition of products of hydrous pyrolysis of organic matter.PETROLEUM SCIENCE.
MLA	Cai, Yu-Wen,et al."Effects of U-ore on the chemical and isotopic composition of products of hydrous pyrolysis of organic matter".PETROLEUM SCIENCE (2017).