Preparation and characterization of single crystals   [Ln(TBPO)(4)(NO3)(2)]NTf2 (Ln = Eu, Gd)

doi:10.1016/j.cclet.2016.06.020

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	Preparation and characterization of single crystals [Ln(TBPO)(4)(NO3)(2)]NTf2 (Ln = Eu, Gd)
	Deng, Chuan-Dong ; Qiao, Yu-Jia ; Chen, Qing-De ; Shen, Xing-Hai
刊名	CHINESE CHEMICAL LETTERS
	2017
关键词	Tri-n-butylphosphine oxide Europium Gadolinium Single crystal LANTHANIDE NITRATE COMPLEXES IONIC LIQUIDS OXIDE EXTRACTION
DOI	10.1016/j.cclet.2016.06.020
英文摘要	Two single crystals [Ln(TBPO)(4)(NO3)(2)]NTf2 (Ln = Eu, Gd) were prepared and characterized by element analysis, single crystal X-ray diffraction, PXRD, FT-IR, TGA and fluorescence spectroscopy. The two compounds have similar coordinate structures, in which the central metal ion is coordinated by four TBPO (Tri-n-butylphosphine oxide) molecules and two bidentate nitrates, while NTf2-(bis(trifluor-(bis(trifluoromethylsulfonyl)imide anion) acts as the counter anion. The packing modes of the two crystals are same. The two single crystals are the focus on 8-coordinate tetra-TRPO complexes (TRPO is Trialkyphosphine oxides). (C) 2016 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. Published by Elsevier B.V. All rights reserved.; National Natural Science Foundation of China [91226112]; SCI(E); 中国科学引文数据库(CSCD); ARTICLE; 1; 19-23; 28
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/476349]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Deng, Chuan-Dong,Qiao, Yu-Jia,Chen, Qing-De,et al. Preparation and characterization of single crystals [Ln(TBPO)(4)(NO3)(2)]NTf2 (Ln = Eu, Gd)[J]. CHINESE CHEMICAL LETTERS,2017.
APA	Deng, Chuan-Dong,Qiao, Yu-Jia,Chen, Qing-De,&Shen, Xing-Hai.(2017).Preparation and characterization of single crystals [Ln(TBPO)(4)(NO3)(2)]NTf2 (Ln = Eu, Gd).CHINESE CHEMICAL LETTERS.
MLA	Deng, Chuan-Dong,et al."Preparation and characterization of single crystals [Ln(TBPO)(4)(NO3)(2)]NTf2 (Ln = Eu, Gd)".CHINESE CHEMICAL LETTERS (2017).