Two-step crosslinked liquid-crystalline elastomer with reversible two-way shape memory characteristics | |
Wang, Yuchang ; Huang, Xuezhen ; Zhang, Jianqi ; Bi, Meng ; Zhang, Jindi ; Niu, Hongyan ; Li, Chensha ; Yu, Haifeng ; Wang, Binsong ; Jiang, Hongrui | |
刊名 | MOLECULAR CRYSTALS AND LIQUID CRYSTALS |
2017 | |
关键词 | Liquid crystalline elastomer Nematic structure Shape memory effect Smart deformable material Sophisticated deformation POLYMER ACTUATORS LIGHT AZOBENZENE MOTION NETWORKS MODULUS |
DOI | 10.1080/15421406.2017.1318025 |
英文摘要 | Liquid-crystalline elastomers (LCEs) possess large and equilibrium reversible anisotropic dimensional change in response to applied stimuli. The deformation behavior demonstrated by current LCE materials under the stimuli are generally determined by their own geometries and the alignment distributions of liquid crystal (LC) units in the LCE matrices. Here we report a LCE whose synthesis was through a two-stage crosslinking coupled with a mechanical reshaping process, where the shape was mechanically reset before the final crosslinking. It demonstrated reversible memory and change between the initial geometries formed during the first crosslinking stage and any reshaped geometries under the stimuli. Its deformation is not influenced by the geometries and the alignment distributions of LC units in the LCE matrix. This characteristic in LCEs holds promise in a wide range of application researches requiring sophisticated functions and smart structures.; University of Wisconsin - Madison Vilas Associates Program - Vilas Trustees; Wisconsin Institutes for Discovery; U.S. National Science Foundation [ECCS 0702095]; SCI(E); ARTICLE; 1; 13-22; 650 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/475822] |
专题 | 化学与分子工程学院 |
推荐引用方式 GB/T 7714 | Wang, Yuchang,Huang, Xuezhen,Zhang, Jianqi,et al. Two-step crosslinked liquid-crystalline elastomer with reversible two-way shape memory characteristics[J]. MOLECULAR CRYSTALS AND LIQUID CRYSTALS,2017. |
APA | Wang, Yuchang.,Huang, Xuezhen.,Zhang, Jianqi.,Bi, Meng.,Zhang, Jindi.,...&Jiang, Hongrui.(2017).Two-step crosslinked liquid-crystalline elastomer with reversible two-way shape memory characteristics.MOLECULAR CRYSTALS AND LIQUID CRYSTALS. |
MLA | Wang, Yuchang,et al."Two-step crosslinked liquid-crystalline elastomer with reversible two-way shape memory characteristics".MOLECULAR CRYSTALS AND LIQUID CRYSTALS (2017). |
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