Nickel-Catalyzed Oxidative Coupling of Unactivated C(sp(3))-H Bonds in   Aliphatic Amides with Terminal Alkynes

doi:10.1021/acs.organomet.6b00529

CORC > 北京大学 > 化学与分子工程学院

	Nickel-Catalyzed Oxidative Coupling of Unactivated C(sp(3))-H Bonds in Aliphatic Amides with Terminal Alkynes
	Luo, Fei-Xian ; Cao, Zhi-Chao ; Zhao, Hong-Wei ; Wang, Ding ; Zhang, Yun-Fei ; Xu, Xing ; Shi, Zhang-Jie
刊名	ORGANOMETALLICS
	2017
关键词	C-H BONDS ALPHA-AMINO-ACIDS DECARBOXYLATIVE ALKYNYLATION ROOM-TEMPERATURE SONOGASHIRA REACTIONS TOLUENE DERIVATIVES GRIGNARD-REAGENTS CARBOXYLIC-ACIDS DIRECT ARYLATION ARYL HALIDES
DOI	10.1021/acs.organomet.6b00529
英文摘要	In this work, we demonstrated Ni-catalyzed oxidative coupling of unactivated C(sp(3))-H bonds with terminal alkynes for construction of C(sp(3))-C(sp) bonds to synthesize alkyl-substituted internal alkynes. Different amides exhibited good compatibility. Preliminary mechanistic studies were conducted to account for this alkynylation.; MOST of China [2013CB228102, 2015CB856600]; NSFC [21332001]; SCI(E); ARTICLE; 1; 18-21; 36
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/475747]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Luo, Fei-Xian,Cao, Zhi-Chao,Zhao, Hong-Wei,et al. Nickel-Catalyzed Oxidative Coupling of Unactivated C(sp(3))-H Bonds in Aliphatic Amides with Terminal Alkynes[J]. ORGANOMETALLICS,2017.
APA	Luo, Fei-Xian.,Cao, Zhi-Chao.,Zhao, Hong-Wei.,Wang, Ding.,Zhang, Yun-Fei.,...&Shi, Zhang-Jie.(2017).Nickel-Catalyzed Oxidative Coupling of Unactivated C(sp(3))-H Bonds in Aliphatic Amides with Terminal Alkynes.ORGANOMETALLICS.
MLA	Luo, Fei-Xian,et al."Nickel-Catalyzed Oxidative Coupling of Unactivated C(sp(3))-H Bonds in Aliphatic Amides with Terminal Alkynes".ORGANOMETALLICS (2017).