Synthesis, Characterization, and Reactivity Studies of Subphthalocyanine   Boron Triflate

doi:10.1021/acs.organomet.6b00754

CORC > 北京大学 > 化学与分子工程学院

	Synthesis, Characterization, and Reactivity Studies of Subphthalocyanine Boron Triflate
	Wang, Zikuan ; Fu, Xuefeng
刊名	ORGANOMETALLICS
	2017
关键词	FRUSTRATED LEWIS PAIRS AXIAL FUNCTIONALIZATION PHYSICAL-PROPERTIES CATALYTIC-ACTIVITY CRYSTAL-STRUCTURES LI/SOCL2 BATTERY BOND-CLEAVAGE FLUORIDE ACTIVATION SERIES
DOI	10.1021/acs.organomet.6b00754
英文摘要	The highly reactive subphthalocyanine boron triflate complex ((subPc)BOTf) was isolated and characterized by X-ray diffraction and spectroscopic methods. The combination of (subPc)BOTf and bis(trimethylsilyl)-amide (LiHMDS) yielded a "kinetically induced" frustrated Lewis pair system capable of activating a variety of substrates such as ethers, amides, and ketones. These reactions demonstrate the high reactivity of (subPc)BOTf toward organic molecules.; Natural Science Foundation of China [21322108, 21571009]; SCI(E); ARTICLE; 2; 285-290; 36
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/475618]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Wang, Zikuan,Fu, Xuefeng. Synthesis, Characterization, and Reactivity Studies of Subphthalocyanine Boron Triflate[J]. ORGANOMETALLICS,2017.
APA	Wang, Zikuan,&Fu, Xuefeng.(2017).Synthesis, Characterization, and Reactivity Studies of Subphthalocyanine Boron Triflate.ORGANOMETALLICS.
MLA	Wang, Zikuan,et al."Synthesis, Characterization, and Reactivity Studies of Subphthalocyanine Boron Triflate".ORGANOMETALLICS (2017).