A Study on the Electro-Optical Properties of Thiol-Ene Polymer Dispersed Cholesteric Liquid Crystal (PDChLC) Films | |
Sun, Yujian ; Gao, Yanzi ; Zhou, Le ; Huang, Jianhua ; Fang, Hua ; Ma, Haipeng ; Zhang, Yi ; Yang, Jie ; Song, Ping ; Zhang, Cuihong ; Zhang, Lanying ; Li, Fasheng ; Zhao, Yuzhen ; Li, Kexuan | |
刊名 | MOLECULES |
2017 | |
关键词 | polymer dispersed cholesteric liquid crystal liquid crystal chiral electro-optical performance INDUCED PHASE-SEPARATION MONOMER CHEMISTRY NANOCOMPOSITES FUNCTIONALITY AZOBENZENE COMPOSITE NETWORK |
DOI | 10.3390/molecules22020317 |
英文摘要 | In this study, a polymer dispersed cholesteric liquid crystal (PDChLC) film obtained via a one-step fabrication technique based on photopolymerization of a thiol-acrylate reaction system was prepared and characterized for the first time. The effects of the chiral dopant, the influence of thiol monomer functionality and content on the morphology and subsequent performance of the PDChLC films were systematically investigated. It was demonstrated that the addition of a small amount of chiral dopant slightly increased the driving voltage, but decreased the off-state transmittance significantly. Furthermore, scanning electron micrographs (SEM) shown that the liquid crystal (LC) droplet size decreased at first and then increased with the increasing amount of thiol monomer functionality, while increasing the thiol content increased the LC droplet size. Correspondingly, the electro-optical switching behavior was directly dependent on LC droplet size. By tuning the raw material composition, PDChLC film with optimized electro-optical performance was prepared.; National Natural Science Foundation [51333001, 51372029, 51402006, 51573003]; Fok Ying Tung Education Foundation [142009]; SCI(E); ARTICLE; 2; 22 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/475368] |
专题 | 化学与分子工程学院 工学院 |
推荐引用方式 GB/T 7714 | Sun, Yujian,Gao, Yanzi,Zhou, Le,et al. A Study on the Electro-Optical Properties of Thiol-Ene Polymer Dispersed Cholesteric Liquid Crystal (PDChLC) Films[J]. MOLECULES,2017. |
APA | Sun, Yujian.,Gao, Yanzi.,Zhou, Le.,Huang, Jianhua.,Fang, Hua.,...&Li, Kexuan.(2017).A Study on the Electro-Optical Properties of Thiol-Ene Polymer Dispersed Cholesteric Liquid Crystal (PDChLC) Films.MOLECULES. |
MLA | Sun, Yujian,et al."A Study on the Electro-Optical Properties of Thiol-Ene Polymer Dispersed Cholesteric Liquid Crystal (PDChLC) Films".MOLECULES (2017). |
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