A Star-Shaped Molecule with Low-Lying Lowest Unoccupied Molecular   Orbital Level, n-Type Panchromatic Electrochromism, and Long-Term   Stability

doi:10.1021/acs.orglett.7b00522

CORC > 北京大学 > 化学与分子工程学院

	A Star-Shaped Molecule with Low-Lying Lowest Unoccupied Molecular Orbital Level, n-Type Panchromatic Electrochromism, and Long-Term Stability
	Yao, Bin ; Zhou, Yue ; Ye, Xichong ; Wang, Rong ; Zhang, Jie ; Wan, Xinhua
刊名	ORGANIC LETTERS
	2017
关键词	POLYCYCLIC AROMATIC-HYDROCARBONS INTRAMOLECULAR ELECTRON-TRANSFER ORGANIC MIXED-VALENCE THIN-FILM TRANSISTORS CHANNEL SEMICONDUCTORS ANTHRAQUINONE IMIDES ANION-RADICALS TRIPHENYLENE TRANSPORT SYSTEMS
DOI	10.1021/acs.orglett.7b00522
英文摘要	An electron-deficient star-shaped molecule based on anthraquinone imide was synthesized and characterized. It showed high electron accommodating capacity and strong electron-withdrawing ability with a low-lying lowest unoccupied molecular orbital (LUMO) of -4.10 eV. In addition, it exhibited panchromatic electrochromism attributed to the simultaneous presence of pi-pi transitions and intervalence charge transfer (IV-CT) upon one-electron reduction, and revealed long-term stability in electron gain and loss due to the proper LUMO energy level and ordered intermolecular assembly.; National Natural Science Foundation of China [20834001]; Research Fund for Doctoral Program of Higher Education of MOE of China [20060001029]; SCI(E); ARTICLE; 8; 1990-1993; 19
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/473910]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Yao, Bin,Zhou, Yue,Ye, Xichong,et al. A Star-Shaped Molecule with Low-Lying Lowest Unoccupied Molecular Orbital Level, n-Type Panchromatic Electrochromism, and Long-Term Stability[J]. ORGANIC LETTERS,2017.
APA	Yao, Bin,Zhou, Yue,Ye, Xichong,Wang, Rong,Zhang, Jie,&Wan, Xinhua.(2017).A Star-Shaped Molecule with Low-Lying Lowest Unoccupied Molecular Orbital Level, n-Type Panchromatic Electrochromism, and Long-Term Stability.ORGANIC LETTERS.
MLA	Yao, Bin,et al."A Star-Shaped Molecule with Low-Lying Lowest Unoccupied Molecular Orbital Level, n-Type Panchromatic Electrochromism, and Long-Term Stability".ORGANIC LETTERS (2017).