One-Dimensional Helical Metal Coordination Polymer: Synthesis and   Structure of Infinite Chain of [Ag-7(S2CNEt2)(6)](n)(+) (as [SbF6](-)   salt) Composed of Ag-6(S2CNEt2)(6) Cluster Units Linked by Ag(I) Ions   via Peculiar Chelating S-S Bites

doi:10.1007/s10876-016-1112-x

CORC > 北京大学 > 化学与分子工程学院

	One-Dimensional Helical Metal Coordination Polymer: Synthesis and Structure of Infinite Chain of [Ag-7(S2CNEt2)(6)](n)(+) (as [SbF6](-) salt) Composed of Ag-6(S2CNEt2)(6) Cluster Units Linked by Ag(I) Ions via Peculiar Chelating S-S Bites
	Zhang, Du-Juan ; Yang, Shi-Yao ; Teo, Boon K.
刊名	JOURNAL OF CLUSTER SCIENCE
	2017
关键词	Silver N,N-diethyl-dithiocarbamate Ag cluster Helical metal coordination polymer OCTAHEDRAL HEXASILVER(I) CLUSTER CRYSTAL-STRUCTURE MOLECULAR-STRUCTURE DISELENOPHOSPHATE LIGANDS ASSEMBLED MATERIALS DFT CALCULATIONS ORGANIC SPACERS COMPLEXES DIETHYLDITHIOCARBAMATE TEMPLATE
DOI	10.1007/s10876-016-1112-x
英文摘要	A new polymeric silver cluster, formulated as [Ag-7(S2CNEt2)(6)][SbF6] (1) was synthesized and characterized by single-crystal X-ray crystallography. The structure can be described as an infinite cationic polymeric helical chain consisting of two [Ag-6(S2CNEt2)(6)] clusters linked by a silver ion tetrahedrally coordinated with four sulfur atoms, two from each of the constituent clusters. The stereochemistry of 1 is classified as a new zeta-modification of silver dithiocarbamate cluster. It is suggested that the constituent [Ag-6(S2CNEt2)(6)] clusters in 1 can be used as building blocks in the construction of 1-D cluster-based metal coordination polymers as well as 2-D or 3-D cluster-based metal-organic frameworks.; NNSFC [21071117, 21471125]; iChEM, Xiamen University; SCI(E); ARTICLE; 3; 1163-1178; 28
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/473809]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Zhang, Du-Juan,Yang, Shi-Yao,Teo, Boon K.. One-Dimensional Helical Metal Coordination Polymer: Synthesis and Structure of Infinite Chain of [Ag-7(S2CNEt2)(6)](n)(+) (as [SbF6](-) salt) Composed of Ag-6(S2CNEt2)(6) Cluster Units Linked by Ag(I) Ions via Peculiar Chelating S-S Bites[J]. JOURNAL OF CLUSTER SCIENCE,2017.
APA	Zhang, Du-Juan,Yang, Shi-Yao,&Teo, Boon K..(2017).One-Dimensional Helical Metal Coordination Polymer: Synthesis and Structure of Infinite Chain of [Ag-7(S2CNEt2)(6)](n)(+) (as [SbF6](-) salt) Composed of Ag-6(S2CNEt2)(6) Cluster Units Linked by Ag(I) Ions via Peculiar Chelating S-S Bites.JOURNAL OF CLUSTER SCIENCE.
MLA	Zhang, Du-Juan,et al."One-Dimensional Helical Metal Coordination Polymer: Synthesis and Structure of Infinite Chain of [Ag-7(S2CNEt2)(6)](n)(+) (as [SbF6](-) salt) Composed of Ag-6(S2CNEt2)(6) Cluster Units Linked by Ag(I) Ions via Peculiar Chelating S-S Bites".JOURNAL OF CLUSTER SCIENCE (2017).