A Six-Coordinate Dysprosium Single-Ion Magnet with TrigonalPrismatic Geometry | |
Liu, Shan-Shan ; Meng, Yin-Shan ; Zhang, Yi-Quan ; Meng, Zhao-Sha ; Lang, Ke ; Zhu, Zhen-Liang ; Shang, Chang-Fang ; Wang, Bing-Wu ; Gao, Song | |
刊名 | INORGANIC CHEMISTRY |
2017 | |
关键词 | MOLECULE MAGNETS URANIUM(III) COMPLEXES LANTHANIDE COMPLEXES ANISOTROPY BARRIER RELAXATION CHEMISTRY |
DOI | 10.1021/acsinorgchern.7b00952 |
英文摘要 | A mononuclar six-coordinate dysprosium complex was synthesized and structurally and magnetically characterized. X-ray structural analyses show trigonalprismatic coordination geometry of the Din center. Slow relaxation of magnetization in the absence of a direct current field and magnetic hysteresis up to 3.0 K could be observed, indicating its single-ion-magnet behavior. Arrhenius fitting and ab initio calculations suggest that the magnetic relaxation process may not occur through the Orbach process at high temperatures under the experimental conditions.; NSFC [21602013, 21621061, 91422302, 21571008]; Beijing Natural Science Foundation [2174072]; General Project of Science and Technology Plan of Beijing Municipal Education Commission [KM201710017001]; Outstanding Young Talents from Beijing Party Committee [2016000020124G060]; Beijing Level College Students Innovation Training Project [2016J00092]; SCI(E); ARTICLE; 13; 7320-7323; 56 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/472273] |
专题 | 化学与分子工程学院 |
推荐引用方式 GB/T 7714 | Liu, Shan-Shan,Meng, Yin-Shan,Zhang, Yi-Quan,et al. A Six-Coordinate Dysprosium Single-Ion Magnet with TrigonalPrismatic Geometry[J]. INORGANIC CHEMISTRY,2017. |
APA | Liu, Shan-Shan.,Meng, Yin-Shan.,Zhang, Yi-Quan.,Meng, Zhao-Sha.,Lang, Ke.,...&Gao, Song.(2017).A Six-Coordinate Dysprosium Single-Ion Magnet with TrigonalPrismatic Geometry.INORGANIC CHEMISTRY. |
MLA | Liu, Shan-Shan,et al."A Six-Coordinate Dysprosium Single-Ion Magnet with TrigonalPrismatic Geometry".INORGANIC CHEMISTRY (2017). |
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