In-Plane Uniaxial Strain in Black Phosphorus Enables the Identification   of Crystalline Orientation

doi:10.1002/smll.201700466

CORC > 北京大学 > 化学与分子工程学院

	In-Plane Uniaxial Strain in Black Phosphorus Enables the Identification of Crystalline Orientation
	Zhang, Shuqing ; Mao, Nannan ; Wu, Juanxia ; Tong, Lianming ; Zhang, Jin ; Liu, Zhirong
刊名	SMALL
	2017
关键词	RAMAN-SPECTROSCOPY CRYSTALLOGRAPHIC ORIENTATION TRANSISTORS DEPENDENCE GRAPHENE
DOI	10.1002/smll.201700466
英文摘要	Identification of the crystalline axis of anisotropic black phosphorus (BP) is important for investigating its physical properties, as well as for optical and electronic applications. Herein, it is showed that by applying in-plane uniaxial strain and measuring the changes of the Raman shifts, the crystalline axis of BP can be reliably determined. The strain effects on the Raman shifts are angle-dependent, and they can be expressed as a combination of the Raman responses under zigzag and armchair strain. Differing from previous polarized optical spectroscopic methods where the Raman intensity is analyzed, the proposed method uses the Raman frequency shift, which is less affected by laser polarization, excitation wavelength, the sample thickness, and the substrate. The effective strain applied on BP from the stretched substrate is estimated, and the results show that only 20 to 40% of the strain can be effectively transferred to BP flakes from a polyethylene terephthalate substrate. Our method provides not only an effective and robust approach to identify the crystalline orientation of layered BP, but it is also a model to extract additional information in strain-related studies. It can also be extended to other 2D anisotropic materials.; National Natural Science Foundation of China [21373015, 21233001, 21573004]; Ministry of Science and Technology [2016YFA0200101, 2016YFA0200104, 2015CB932400]; China Postdoctoral Science Foundation [2015M580010]; SCI(E); ARTICLE; 30; 13
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/471515]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Zhang, Shuqing,Mao, Nannan,Wu, Juanxia,et al. In-Plane Uniaxial Strain in Black Phosphorus Enables the Identification of Crystalline Orientation[J]. SMALL,2017.
APA	Zhang, Shuqing,Mao, Nannan,Wu, Juanxia,Tong, Lianming,Zhang, Jin,&Liu, Zhirong.(2017).In-Plane Uniaxial Strain in Black Phosphorus Enables the Identification of Crystalline Orientation.SMALL.
MLA	Zhang, Shuqing,et al."In-Plane Uniaxial Strain in Black Phosphorus Enables the Identification of Crystalline Orientation".SMALL (2017).