Synthesis of dibromo- and tetrabromo-bipyrrolines and their   corresponding 2,6-diazasemibullvalene derivatives

doi:10.1039/c7qo00287d

CORC > 北京大学 > 化学与分子工程学院

	Synthesis of dibromo- and tetrabromo-bipyrrolines and their corresponding 2,6-diazasemibullvalene derivatives
	Huang, Zhe ; Zhan, Ming ; Zhang, Shaoguang ; Luo, Qian ; Zhang, Wen-Xiong ; Xi, Zhenfeng
刊名	ORGANIC CHEMISTRY FRONTIERS
	2017
关键词	COPE REARRANGEMENT BISHOMOAROMATIC SEMIBULLVALENES STRUCTURAL-CHARACTERIZATION REACTION CHEMISTRY HOMOAROMATICITY BARBARALANES STABILIZATION SUBSTITUENTS SPECTROSCOPY MOLECULES
DOI	10.1039/c7qo00287d
英文摘要	Treatment of. Delta(1)-dipyrrolines with NBS afforded alpha,alpha'-dibromo-Delta(1)-bipyrrolines and alpha, alpha, alpha', alpha'- tetrabromo. Delta(1)-bipyrrolines respectively with excellent selectivity depending on the amount of NBS. All these multibromo- substituted. Delta(1)-bipyrrolines could be efficiently transformed into their corresponding 2,6-diazasemibullvalene derivatives via reduction with lithium. An unprecedented rearrangement of 4,8-dibromo-2,6-diazasemibullvalene afforded a new type of bipyrroline derivative.; Natural Science Foundation of China [21372012, 21690061]; SCI(E); ARTICLE; 9; 1785-1788; 4
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/471232]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Huang, Zhe,Zhan, Ming,Zhang, Shaoguang,et al. Synthesis of dibromo- and tetrabromo-bipyrrolines and their corresponding 2,6-diazasemibullvalene derivatives[J]. ORGANIC CHEMISTRY FRONTIERS,2017.
APA	Huang, Zhe,Zhan, Ming,Zhang, Shaoguang,Luo, Qian,Zhang, Wen-Xiong,&Xi, Zhenfeng.(2017).Synthesis of dibromo- and tetrabromo-bipyrrolines and their corresponding 2,6-diazasemibullvalene derivatives.ORGANIC CHEMISTRY FRONTIERS.
MLA	Huang, Zhe,et al."Synthesis of dibromo- and tetrabromo-bipyrrolines and their corresponding 2,6-diazasemibullvalene derivatives".ORGANIC CHEMISTRY FRONTIERS (2017).