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In-situ modification of carbon fibers with hyperbranched polyglycerol via anionic ring-opening polymerization for use in high-performance composites
Gao, Bo ; Zhang, Jing ; Hao, Zhenna ; Huo, Lujie ; Zhang, Ruliang ; Shao, Lu
刊名CARBON
2017
关键词ENHANCED MECHANICAL-PROPERTIES GRAPHENE OXIDE INTERFACIAL PROPERTIES EPOXY COMPOSITES SURFACE FUNCTIONALIZATION NANOWIRE INTERPHASE PLASMA TREATMENT ZINC-OXIDE STABILITY COATINGS
DOI10.1016/j.carbon.2017.08.008
英文摘要In this study, hyperbranched polyglycerol (HPG) is chemically bound onto carbon fiber (CF) surface by anionic ring-opening polymerization for linking fiber and matrix to release interior and exterior applied forces. To explore the optimal conditions for the successful hyperbranched polymerization of glycidol on the carbon fiber, various characterization techniques were employed. The atomic force microscope quantitative nanomechanical mapping results reveal that the HPG can significantly improve interfacial status between carbon fiber and epoxy matrix. Compared with the mechanical properties of desized fiber based composites, both interfacial shear strength and interlaminar shear strength of HPG grafted fiber/epoxy composites increase by 90.69% and 49.83%, respectively. The adjustable size of HPG grafted on CF endorse the CF modification strategy with the unique characteristic, which can design the optimized interface between CF and resin to meet various scientific and technical demands. (C) 2017 Elsevier Ltd. All rights reserved.; National Natural Science Fund Program of China [51403119, 21676063, U1462103]; SCI(E); ARTICLE; 548-557; 123
语种英语
内容类型期刊论文
源URL[http://ir.pku.edu.cn/handle/20.500.11897/470666]  
专题化学与分子工程学院
推荐引用方式
GB/T 7714
Gao, Bo,Zhang, Jing,Hao, Zhenna,et al. In-situ modification of carbon fibers with hyperbranched polyglycerol via anionic ring-opening polymerization for use in high-performance composites[J]. CARBON,2017.
APA Gao, Bo,Zhang, Jing,Hao, Zhenna,Huo, Lujie,Zhang, Ruliang,&Shao, Lu.(2017).In-situ modification of carbon fibers with hyperbranched polyglycerol via anionic ring-opening polymerization for use in high-performance composites.CARBON.
MLA Gao, Bo,et al."In-situ modification of carbon fibers with hyperbranched polyglycerol via anionic ring-opening polymerization for use in high-performance composites".CARBON (2017).
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