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Template-free synthesis of titania architectures with controlled morphology evolution
Cheng, Ting ; Zhang, Guoqiang ; Xia, Yonggao ; Ji, Qing ; Xiao, Ying ; Wang, Xiaoyan ; Wang, Meimei ; Liu, Rui ; Qiu, Bao ; Chen, Guoxin ; Chen, Huifeng ; Sun, Zaicheng ; Meng, Jian-Qiang ; Liu, Zhaoping ; Xiao, Tonghu ; Sun, Ling-Dong ; Yan, Chun-Hua ; Cheng, Ya-Jun
刊名JOURNAL OF MATERIALS SCIENCE
2016
关键词SENSITIZED SOLAR-CELLS LITHIUM-ION BATTERIES HOLLOW SPHERES ENERGY APPLICATIONS HIERARCHICAL TIO2 DIOXIDE NANOMATERIALS STORAGE ANATASE PHOTOCATALYSIS
DOI10.1007/s10853-015-9713-6
英文摘要Template-free synthesis of TiO2 architectures with controlled morphology evolution has been developed through solvothermal reaction in 1,4-dioxane. By simply varying the molar ratio of the concentrated HCl over Titanium isopropoxide (TTIP) from 0 to 5.0, series of morphologies including nanoparticle-built microspheres, nanoparticle-built microspheres decorated with nanorods, nanorod cauliflowers, and nanorod dendrites have been obtained. The influence of several key factors on the morphology control of TiO2 has been systematically investigated. These parameters include the mass (molar) ratio of HCl/TTIP, solvothermal reaction temperature and time, acid species (concentrated nitric acid), and solvent type (tetrahydrofuran and 1,3-dioxane). The mechanism for the formation of the TiO2 architectures with controlled morphology evolution has been discussed. The application of the TiO2 architectures as water splitting photocatalyst and lithium-ion battery anode has been demonstrated. And the corresponding structure-property correlation has been discussed.; Natural Science Foundation of China [51103172]; Zhejiang Non-profit Technology Applied Research Program [2013C33190]; Beijing National Laboratory for Molecular Science [20140138]; Ningbo Key Laboratory of Polymer Materials; SCI(E); ARTICLE; chengyj@nimte.ac.cn; 8; 3941-3956; 51
语种英语
内容类型期刊论文
源URL[http://ir.pku.edu.cn/handle/20.500.11897/438409]  
专题化学与分子工程学院
推荐引用方式
GB/T 7714
Cheng, Ting,Zhang, Guoqiang,Xia, Yonggao,et al. Template-free synthesis of titania architectures with controlled morphology evolution[J]. JOURNAL OF MATERIALS SCIENCE,2016.
APA Cheng, Ting.,Zhang, Guoqiang.,Xia, Yonggao.,Ji, Qing.,Xiao, Ying.,...&Cheng, Ya-Jun.(2016).Template-free synthesis of titania architectures with controlled morphology evolution.JOURNAL OF MATERIALS SCIENCE.
MLA Cheng, Ting,et al."Template-free synthesis of titania architectures with controlled morphology evolution".JOURNAL OF MATERIALS SCIENCE (2016).
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