A distinct magnetic anisotropy enhancement in mononuclear   dysprosium-sulfur complexes by controlling the Dy-ligand bond length

doi:10.1039/c6dt01089j

CORC > 北京大学 > 化学与分子工程学院

	A distinct magnetic anisotropy enhancement in mononuclear dysprosium-sulfur complexes by controlling the Dy-ligand bond length
	Liu, Shan-Shan ; Lang, Ke ; Zhang, Yi-Quan ; Yang, Qian ; Wang, Bing-Wu ; Gao, Song
刊名	DALTON TRANSACTIONS
	2016
关键词	SINGLE-MOLECULE-MAGNET ION MAGNET LANTHANIDE COMPLEXES ENERGY BARRIER CHEMISTRY BLOCKING BEHAVIOR SYMMETRY DESIGN
DOI	10.1039/c6dt01089j
英文摘要	In a field-induced single-ion magnet [(dtc)(3)Dy(phen)] (dtc(-) = diethyldithiocarbamate anion), replacing two of the S-based dtc(-) ligands with O-based dbm(-) ligands (dbm(-) = dibenzoylmethanoate anion) leads to a significant enhancement of magnetic anisotropy, yielding a rarely reported sulfur-ligated lanthanide-based single-ion magnet [(dbm)(2)Dy(dtc)(phen)]. Ab initio calculations reveal that the g(z) value of [(dbm)(2)Dy(dtc)(phen)] is much larger than that of [(dtc)(3)Dy(phen)], consistent with the experimental results.; NSFC [21290171, 21321001, 91422302, 21571008]; National Basic Research Program of China [2013CB933401]; Research Fund of Beijing Institute of Petrochemical Technology [15031862005/003]; SCI(E); EI; ARTICLE; wangbw@pku.edu.cn; gaosong@pku.edu.cn; 19; 8149-8153; 45
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/438021]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Liu, Shan-Shan,Lang, Ke,Zhang, Yi-Quan,et al. A distinct magnetic anisotropy enhancement in mononuclear dysprosium-sulfur complexes by controlling the Dy-ligand bond length[J]. DALTON TRANSACTIONS,2016.
APA	Liu, Shan-Shan,Lang, Ke,Zhang, Yi-Quan,Yang, Qian,Wang, Bing-Wu,&Gao, Song.(2016).A distinct magnetic anisotropy enhancement in mononuclear dysprosium-sulfur complexes by controlling the Dy-ligand bond length.DALTON TRANSACTIONS.
MLA	Liu, Shan-Shan,et al."A distinct magnetic anisotropy enhancement in mononuclear dysprosium-sulfur complexes by controlling the Dy-ligand bond length".DALTON TRANSACTIONS (2016).